Acylation and Alkylation
Michael Röper, Eugen Gehrer, Thomas Narbeshuber,
Wolfgang Siegel,
Thomas Narbeshuber
BASF Aktiengesellschaft, Ludwigshafen, Germany
Search for more papers by this authorMichael Röper, Eugen Gehrer, Thomas Narbeshuber,
Wolfgang Siegel,
Thomas Narbeshuber
BASF Aktiengesellschaft, Ludwigshafen, Germany
Search for more papers by this authorAbstract
The article contains sections titled:
1. |
Introduction |
1.1. |
Catalysts |
1.1.1. |
Acidic Catalysts |
1.1.2. |
Basic Catalysts |
1.1.3. |
Organometallic Catalysts |
1.2. |
Alkylating and Acylating Agents |
1.3. |
Mechanism |
1.3.1. |
Alkylation |
1.3.2. |
Acylation |
2. |
Alkylation and Acylation of Aromatic Compounds |
2.1. |
Alkylation |
2.1.1. |
Alkylation of Benzene |
2.1.2. |
Cycloalkylation |
2.1.3. |
Alkylation of Substituted Benzenes |
2.1.4. |
Alkylation of Phenols |
2.1.5. |
Alkylation of Aromatic Amines |
2.1.6. |
Alkylation of Heteroaromatic Compounds and Related Substrates |
2.1.7. |
Miscellaneous Alkylation Reactions |
2.2. |
Acylation |
2.2.1. |
Acylation of Benzene and Benzene Derivatives |
2.2.2. |
Acylation of Polynuclear Aromatic Compounds |
2.2.3. |
Acylation of Heteroaromatic Compounds |
2.2.4. |
Acylation of Nonbenzenoid Aromatic Compounds |
2.2.5. |
Miscellaneous Acylation Reactions |
3. |
Acylation and Alkylation of Aliphatic Hydrocarbons |
4. |
N-Alkylation and N-Acylation |
4.1. |
N-Alkylation |
4.1.1. |
N-Alkylation by Alcohols or Ethers |
4.1.2. |
N-Alkylation by Alkyl Halides |
4.1.3. |
N-Alkylation by Olefins |
4.1.4. |
N-Alkylation by Carbonyl Compounds (Reductive Alkylation) |
4.2. |
N-Acylation |
5. |
O-Alkylation and O-Acylation |
5.1. |
Synthesis of Esters |
5.2. |
Synthesis of Anhydrides |
5.3. |
Synthesis of Ethers |
6. |
CH-Alkylation and CH-Acylation of Nonaromatic Compounds |
7. |
Synthesis of Metal Alkyls |
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Further Reading
-
M. Bandini,
A. Umani-Ronchi (eds.):
Catalytic Asymmetric Friedel-Crafts Alkylations,
Wiley-VCH,
Weinheim
2009.
10.1002/9783527626977 Google Scholar
-
F. Cavani,
G. Centi,
S. Perathoner,
F. Trifiró (eds.):
Sustainable Industrial Processes,
Wiley-VCH,
Weinheim
2009.
10.1002/9783527629114 Google Scholar
- G. P. Chiusoli, P. M. Maitlis (eds.): Metal-Catalysis in Industrial Organic Processes, Royal Society of Chemistry, Cambridge 2006.
-
S. Kulprathipanja (ed.):
Zeolites in Industrial Separation and Catalysis,
Wiley-VCH,
Weinheim
2010.
10.1002/9783527629565 Google Scholar
-
J. Otera,
J. Nishikido:
Esterification,
2nd ed.,
Wiley-VCH,
Weinheim
2010.
10.1002/9783527627622 Google Scholar
- G. Sartori, R. Maggi: Friedel-Crafts Acylation Reactions, CRC Taylor & Francis, Boca Raton, FL 2010.
-
B. V. Vora,
J. A. Kocal,
P. T. Barger,
R. J. Schmidt,
J. A. Johnson:
Alkylation,
Kirk Othmer Encyclopedia of Chemical Technology,
5th edition,
vol. 4,
p. 169–203,
John Wiley & Sons,
Hoboken, NJ,
2004,
online DOI: 10.1002/0471238961.0112112508011313.a01.pub2
10.1002/0471238961.0112112508011313.a01.pub2 Google Scholar
- F. Zaragoza Dörwald: Side Reactions in Organic Synthesis, Wiley-VCH, Weinheim 2005.
