Aldol Reaction—Homogeneous
Li-Wen Xu,
Li Li,
Yong-Feng Cai,
Li-Wen Xu
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorLi Li
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorYong-Feng Cai
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorLi-Wen Xu,
Li Li,
Yong-Feng Cai,
Li-Wen Xu
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorLi Li
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorYong-Feng Cai
Hangzhou Normal University, Hangzhou, People's Republic of China
Search for more papers by this authorFirst published: 15 February 2011
Abstract
The aldol reaction is one of the oldest and important methods for the construction of carbon–carbon bonds in organic chemistry. Over the last 30 years, tremendous efforts have resulted in the development of many highly sophisticated and efficient catalytic methods of modern aldol reactions in catalytic chemo-, regio-, enantio-, and diastereoselective manners. This review outlined those efforts in homogeneous catalysis and discussed with selected examples (331 publications) according to the different elemental types of catalysts, for example, transition metals and rare earth metals based Lewis acids, main group metals based catalysts, multifunctional catalysts, and metal-free catalysts.
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