Inorganic Syntheses

Book
TOC

Actions

Share

About this book

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Author Bios

Alan Graham MacDiarmid, ONZ FRS was a New Zealand-born American chemist, and one of three recipients of the Nobel Prize for Chemistry in 2000.

Free Access

Dicarbonyl(η⁵-Cyclopentadienylxthio-Carbonyl)Iron(1 +) Hexafluorophosphate(1 -) and Dicarbonyl(η ⁵-Cyclopentadienyl)-[(Methylthio)Thiocarbonyl]Iron (Pages: 100-103)

R. Duane Dombek, Robert J. Angelici, Ian S. Butler, Daniel Cozak,

Potassium cis-[Diaquabis(Oxalato)Chromate(III)] Dihydrate and Potassium trans-[Diaquabis(Oxalato)- Chromate(III)] Trihydrate (Pages: 147-152)

George B. Kauffman, Davey Faoro, Joe Gliksman, Jay H. Worrell,

Share

Inorganic Syntheses

About this book

Author Bios

Table of Contents

Frontmatter (Pages: i-xii)

Part 1 : Chapter One METAL HYDRIDES

Magnesium Dihydride (Pages: 1-5)

Zinc Dihydride (Pages: 6-9)

Lithium Trihydridozincate(1-) and Lithium Tetrahydridozincate(2 -) (Pages: 9-13)

Sodium Trihydridodimethyldizincate(1-) and Sodium Trihydridozincate(1-) (Pages: 13-16)

Calcium Bis[Tetrahydroborate(1-) (Pages: 17-21)

Quaternary Ammonium and Phosphonium Heptahydrodiborates (Pages: 21-26)

Potassium Tri(sec-Butyl)Hydroborate(1-) (Pages: 26-30)

Bis(Dimethylamino)Borane (Pages: 30-32)

Bis-μ-(Dimethylamino)-Diborane(6) (Pages: 32-34)

μ-(Dimethylamino)-Diborane(6) (Pages: 34-36)

Trihydrido(Trimethylamine)Aluminum and (Diethylamino)Hydridoaluminum Complexes (Pages: 36-42)

Trihydrido(Trimethylamine)Gallium (Pages: 42-45)

Lithium Tetrahydridogallate(1-) (Pages: 45-47)

Sodium and Potassium Tetrahydridogallate(1 -) (Pages: 48-53)

Hydrido Phosphine Arene Complexes of Molybdenum (Pages: 54-61)

Bis[Ethylenebis(Diphenylphosphine)] Hydrido(2,4-Pentanedionato)Molybdenum(II) (Pages: 61-64)

Tris(Dimethylphenylphosphine)Pentahydrido-Rhenium (V) (Pages: 64-66)

Dodecacarbonyltri-μ-Hydrido-Triangulo-Trir Henium(I) (Pages: 66-68)

Bis[Ethylenebis(Diphenylphosphine)]-Hydridoiron Complexes (Pages: 69-72)

Hydridonitrosyltris(Triphenylphosphine)- Ruthenium(I) (Pages: 73-74)

Dihydridotetrakis(Triphenylphosphine)- Ruthenium(II) (Pages: 75-77)

Hydrido[η6-Phenyl)Diphenylphosphine]-Bis(Triphenylphosphine)Ruthenium(II) Tetrafluoroborate(1 -) (Pages: 77-78)

(Acetato)Hydridotris)Triphenylphosphine)- Ruthenium(II) (Pages: 79-80)

Hydridobis[(+)-Diop]Rhodium(I) (Pages: 81-83)

Nickel and Palladium Chlorohydridobis-(Phosphine) Complexes (Pages: 83-88)

Hydrido[Tetrahydroborato(1-)] Nickel and Palladium Complexes (Pages: 88-91)

Bis(η5-Cyclopentadienyl) [Tetrahydroborato(1−)]Titanium (Pages: 91-94)

Part 2 : Chapter Two CARBONYL, PHOSPHINE, OLEFIN, AND RELATED TRANSITION METAL COMPLEXES

(Carbene)Pentacarbonyl Complexes of Chromium and Tungsten (Pages: 95-100)

Dicarbonyl(η5-Cyclopentadienylxthio-Carbonyl)Iron(1 +) Hexafluorophosphate(1 -) and Dicarbonyl(η 5-Cyclopentadienyl)-[(Methylthio)Thiocarbonyl]Iron (Pages: 100-103)

Tricarbonyl-(η 5-Cyclopentadienyl)Silyl Complexes of Chromium, Molybdenum, and Tungsten (Pages: 104-109)

Phosphine Complexes of Rhenium (Pages: 110-112)

π-Cyclooctenyl-π-L,5-Cycloocta-Dienecobalt (Pages: 112-115)

Dodecacarbonyltetrarhodium (Pages: 115-117)

Olefin, Acetylene, Phosphine, Isocyanide, and Diazene Complexes of Nickel(0) (Pages: 117-124)

(Carboxylato)(Triphenylphosphine) Complexes of the Platinum Metals (Pages: 124-132)

trans-[Chloroethylbis(Triethylphosphine)- Platinum(II)] (Pages: 132-134)

Tetrakis(T-Butyl Isocyanide)Di-μ-Chloro-Dipalladium(I) (Pages: 134-137)

Part 3 : Chapter Three OTHER TRANSITION METAL COMPOUNDS

Iron(II) and Cobalt(III) Clathrochelates Derived from Dioximes (Pages: 139-147)

Potassium cis-[Diaquabis(Oxalato)Chromate(III)] Dihydrate and Potassium trans-[Diaquabis(Oxalato)- Chromate(III)] Trihydrate (Pages: 147-152)

Cobalt(III), Rhodium(III), and Iridium(III) Carbonato Complexes of the Pentaammine Type (Pages: 152-155)

Technetium(VII) Oxide (Pages: 155-158)

Part 4 : Chapter Four MAIN GROUP COMPOUNDS

Tris(Dialkylamino)Boranes (Pages: 159-161)

Tris(N-Methylanilino)Borane (Pages: 162-164)

1,3-Diaza-2-Boracycloalkanes (Pages: 164-167)

Gallium Trichloride (Pages: 167-172)

Cyclopentadienylsilane and (Methylcyclopentadienyl)Silane (Pages: 172-175)

Cyclopentadienylgermane (Pages: 176-178)

Cyclopentadienyltrimethylstannane (Pages: 178-181)

Bis(Trimethyltin) Oxide: (Hexamethyldistannoxane) (Pages: 181-183)

Methyldiphenylphosphine Oxide and Dimethylphenylphosphine Oxide (Pages: 183-185)

Lithium Diphenylphosphide and Diphenyl(Trimethylsilyl)Phosphine (Pages: 186-188)

Pentathiazyl, [S5N5]+, Salts (Pages: 188-192)

Importance of Excess Base in the Synthesis of Sodium Monothiophosphate: (Sodium Phosphorothioate) (Pages: 193-194)

Appendix: Cautionary Note Concerning the Storing and Handling of Tetrasulfur Tetranitride, S4N4 (Pages: 197-199)

Index of Contributers (Pages: 201-203)

Subject Index (Pages: 205-216)

Formula Index (Pages: 217-223)

Tools

Hydrido[η⁶-Phenyl)Diphenylphosphine]-Bis(Triphenylphosphine)Ruthenium(II) Tetrafluoroborate(1 -) (Pages: 77-78)

Bis(η⁵-Cyclopentadienyl) [Tetrahydroborato(1−)]Titanium (Pages: 91-94)

Dicarbonyl(η⁵-Cyclopentadienylxthio-Carbonyl)Iron(1 +) Hexafluorophosphate(1 -) and Dicarbonyl(η ⁵-Cyclopentadienyl)-[(Methylthio)Thiocarbonyl]Iron (Pages: 100-103)

Tricarbonyl-(η ⁵-Cyclopentadienyl)Silyl Complexes of Chromium, Molybdenum, and Tungsten (Pages: 104-109)

Pentathiazyl, [S₅N₅]⁺, Salts (Pages: 188-192)

Appendix: Cautionary Note Concerning the Storing and Handling of Tetrasulfur Tetranitride, S₄N₄ (Pages: 197-199)