Tris[diphenyl(2-pyridyl)phosphine]-μ3-iodo-tri-μ3-sulfido-sulfidotrisilvertungsten dichloromethane hemisolvate
Abstract
The title compound, [Ag3WIS4(C17H14NP)3]·0.5CH2Cl2, is a cubane-type heterometallic cluster containing diphenyl(2-pyridyl)phosphine (Ph2PPy). The pyridyl group of Ph2PPy remains uncoordinated, so the Ph2PPy ligand is monodentate and coordinates to one Ag atom. The W atom and three Ag atoms form a distorted tetrahedral geometry, capped by one I atom and three S atoms.