Spatial Control of Substitutional Dopants in Hexagonal Monolayer WS2: The Effect of Edge Termination (Small 6/2023)
Tianyi Zhang
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorMingzu Liu
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorKazunori Fujisawa
Research Initiative for Supra-Materials, Shinshu University, Nagano, 380–8553 Japan
Search for more papers by this authorMichael Lucking
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Search for more papers by this authorKory Beach
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA, 94550 USA
Search for more papers by this authorFu Zhang
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorMaruda Shanmugasundaram
HORIBA Instruments Inc, Piscataway, NJ, 08854 USA
Search for more papers by this authorWilliam Murray
Department of Electrical Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorYu Lei
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Shenzhen, 518055 China
Search for more papers by this authorZhuohang Yu
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorDavid Sanchez
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorZhiwen Liu
Department of Electrical Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorHumberto Terrones
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Search for more papers by this authorAna Laura Elías
Department of Physics, Binghamton University, Binghamton, NY, 13902 USA
Search for more papers by this authorMauricio Terrones
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Chemistry, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorTianyi Zhang
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorMingzu Liu
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorKazunori Fujisawa
Research Initiative for Supra-Materials, Shinshu University, Nagano, 380–8553 Japan
Search for more papers by this authorMichael Lucking
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Search for more papers by this authorKory Beach
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA, 94550 USA
Search for more papers by this authorFu Zhang
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorMaruda Shanmugasundaram
HORIBA Instruments Inc, Piscataway, NJ, 08854 USA
Search for more papers by this authorWilliam Murray
Department of Electrical Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorYu Lei
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Shenzhen, 518055 China
Search for more papers by this authorZhuohang Yu
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorDavid Sanchez
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorZhiwen Liu
Department of Electrical Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorHumberto Terrones
Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, Troy, NY, 12180 USA
Search for more papers by this authorAna Laura Elías
Department of Physics, Binghamton University, Binghamton, NY, 13902 USA
Search for more papers by this authorMauricio Terrones
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802 USA
Center for 2-Dimensional and Layered Materials, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Physics, The Pennsylvania State University, University Park, PA, 16802 USA
Department of Chemistry, The Pennsylvania State University, University Park, PA, 16802 USA
Search for more papers by this authorGraphical Abstract
The Effect of Edge Termination
In article number 2205800, Humberto Terrones, Ana Laura Elías, Mauricio Terrones, and co-workers demonstrate the importance of atomic edge termination in determining the spatial distribution of substitutional dopants in 2D transition metal dichalcogenide (TMD) hexagonal monolayers. Preferential iron and vanadium doping occurs on the sulfur-terminated edges of the hexagonal monolayers, causing a decrease in photoluminescence intensity and forming binary optical/electrical domains.
