Maneuvering the Peroxidase-Like Activity of Palladium-Based Nanozymes by Alloying with Oxophilic Bismuth for Biosensing
Shiyu Xia
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorFengxia Wu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Search for more papers by this authorLu Cheng
National Engineering Research Center for New Material Synthesis of Rubber and Plastics, Yanshan Branch of Beijing Chemical Research Institute, Sinopec, Beijing, 102500 China
Search for more papers by this authorHaibo Bao
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Search for more papers by this authorWenping Gao
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorJin Duan
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCorresponding Author
Wenxin Niu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Guobao Xu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorShiyu Xia
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorFengxia Wu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Search for more papers by this authorLu Cheng
National Engineering Research Center for New Material Synthesis of Rubber and Plastics, Yanshan Branch of Beijing Chemical Research Institute, Sinopec, Beijing, 102500 China
Search for more papers by this authorHaibo Bao
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
Search for more papers by this authorWenping Gao
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorJin Duan
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
Search for more papers by this authorCorresponding Author
Wenxin Niu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Guobao Xu
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 China
University of Science and Technology of China, Hefei, Anhui, 230026 China
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
Engineering the catalytic performance of nanozymes is of vital importance for their broad applications in biological analysis, cancer treatment, and environmental management. Herein, a strategy to boost the peroxidase-like activity of Pd-based nanozymes with oxophilic metallic bismuth (Bi) is demonstrated, which is based on the incorporation of oxophilic Bi in the Pd-based alloy nanocrystals (NCs). To synthesize PdBi alloy NCs, a seed-mediated method is employed with the assistance of underpotential deposition (UPD) of Bi on Pd. The strong interaction of Bi atoms with Pd surfaces favors the formation of alloy structures with controllable shapes and excellent monodispersity. More importantly, the PdBi NCs show excellent peroxidase-like activities compared with pristine Pd NCs. The structure–function correlations for the PdBi nanozymes are elucidated, and an indirect colorimetric method based on cascade reactions to determine alkaline phosphatase (ALP) is established. This method has good linear range, low detection limit, excellent selectivity, and anti-interference. Collectively, this work not only provides new insights for the design of high-efficiency nanozymes, expands the colorimetric sensing platform based on enzyme cascade reactions, but also represents a new example for UPD-directed synthesis of alloy NCs.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
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| smll202205997-sup-0001-SuppMat.pdf2.2 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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