Volume 11, Issue 47 pp. 6278-6284
Communication

Hydrophilic Nitrogen and Sulfur Co-doped Molybdenum Carbide Nanosheets for Electrochemical Hydrogen Evolution

Huixiang Ang

Huixiang Ang

Energy Research Institute @ NTU (ERI@N), Interdisciplinary Graduate School, Nanyang Technological University, Singapore, 637553 Singapore

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Hui Teng Tan

Hui Teng Tan

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Zhi Min Luo

Zhi Min Luo

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Yu Zhang

Yu Zhang

Energy Research Institute @ NTU (ERI@N), Interdisciplinary Graduate School, Nanyang Technological University, Singapore, 637553 Singapore

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Yuan Yuan Guo

Yuan Yuan Guo

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Guilue Guo

Guilue Guo

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Hua Zhang

Hua Zhang

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

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Qingyu Yan

Corresponding Author

Qingyu Yan

Energy Research Institute @ NTU (ERI@N), Interdisciplinary Graduate School, Nanyang Technological University, Singapore, 637553 Singapore

School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798 Singapore

E-mail: [email protected]Search for more papers by this author
First published: 03 November 2015
Citations: 183

Graphical Abstract

Nitrogen and sulfur dual-doped Mo2C nanosheets provide low operating potential (−86 mV for driving 10 mA cm−2 of current density). Co-doping of N and S heteroatoms can improve the wetting property of the Mo2C electrocatalyst in aqueous solution and induce synergistic effects via σ-donation and π-back donation with hydronium cation.

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