One-pot synthesis of polyaniline doped with transition metal ions using H2O2 as oxidant†
Corresponding Author
Q. Huang
Department of Materials Science and Engineering, Ynnnan University, Kunming, Yunnan, 650091 PR China
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan, 650091 PR China
Correspondence to: H. Qiang and J. Liu, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, PR China. E-mail [email protected]; [email protected]
Search for more papers by this authorG. Chen
Department of Materials Science and Engineering, Ynnnan University, Kunming, Yunnan, 650091 PR China
Search for more papers by this authorCorresponding Author
J. Liu
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan, 650091 PR China
Correspondence to: H. Qiang and J. Liu, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, PR China. E-mail [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Q. Huang
Department of Materials Science and Engineering, Ynnnan University, Kunming, Yunnan, 650091 PR China
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan, 650091 PR China
Correspondence to: H. Qiang and J. Liu, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, PR China. E-mail [email protected]; [email protected]
Search for more papers by this authorG. Chen
Department of Materials Science and Engineering, Ynnnan University, Kunming, Yunnan, 650091 PR China
Search for more papers by this authorCorresponding Author
J. Liu
Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan, 650091 PR China
Correspondence to: H. Qiang and J. Liu, Key Laboratory of Medicinal Chemistry for Natural Resource, Ministry of Education, School of Chemical Science and Technology, Yunnan University, Kunming, Yunnan 650091, PR China. E-mail [email protected]; [email protected]
Search for more papers by this authorThis article is published in Polymers for Advanced Technologies as a special issue on 2014 Global Conference on Polymer and Composite Materials (PCM 2014), edited by Prof. Moshe Narkis.
Abstract
Polyanilines (PANIs) doped with Zn2+ and Cu2+ were synthesized by H2O2 oxidative polymerization of aniline in the presence of corresponding metal chloride in solution. The products were characterized by elemental analysis, UV-Vis-NIR, FTIR and Raman spectroscopies. Scanning electron micrograph was employed to examine the morphology of PANIs fabricated in the presence of different transition metals. Experimental results showed that transition metal ions had been successfully incorporated into the polymer, and there was a strong interaction between the transition metal ions and the PANI chains. The electrical conductivity of PANI doped with Zn2+ and Cu2+ is 0.37 and 0.21 S/cm, respectively, which is higher than that of HCl doping PANI corresponding to 0.052 S/cm. The cyclic voltammetric study has indicated that incorporation of metal ions in PANI backbone results in increasing of specific capacitance compared to that of HCl doping PANI. Copyright © 2014 John Wiley & Sons, Ltd.
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