Construction of eco-friendly corrosion inhibitor lignin derivative with excellent corrosion-resistant behavior in hydrochloric acid solution
Chao Gao
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorXin Zhao
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorKeyin Liu
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorXinyu Dong
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorCorresponding Author
Shoujuan Wang
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Correspondence Shoujuan Wang and Fangong Kong, The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, 250353 Jinan, China.
Email: [email protected] (S. W.) and [email protected] (F. K.)
Search for more papers by this authorCorresponding Author
Fangong Kong
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Correspondence Shoujuan Wang and Fangong Kong, The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, 250353 Jinan, China.
Email: [email protected] (S. W.) and [email protected] (F. K.)
Search for more papers by this authorChao Gao
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorXin Zhao
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorKeyin Liu
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorXinyu Dong
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Search for more papers by this authorCorresponding Author
Shoujuan Wang
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Correspondence Shoujuan Wang and Fangong Kong, The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, 250353 Jinan, China.
Email: [email protected] (S. W.) and [email protected] (F. K.)
Search for more papers by this authorCorresponding Author
Fangong Kong
The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Shandong Academy of Sciences, Qilu University of Technology, Jinan, China
Correspondence Shoujuan Wang and Fangong Kong, The State Key Laboratory of Bio-based Material and Green Papermaking, Key Laboratory of Pulp and Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology, Shandong Academy of Sciences, 250353 Jinan, China.
Email: [email protected] (S. W.) and [email protected] (F. K.)
Search for more papers by this authorAbstract
Organic corrosion inhibitors from natural plant resources have received extensive attention in recent years. Herein, an eco-friendly corrosion inhibitor lignin–(2,3-epoxypropyl)trimethyl ammonium chloride (EPTAC) was successfully prepared by grafting EPTAC to kraft lignin. The inhibiting efficiency and its inhibition mechanism were investigated using electrochemical methods, adsorption thermodynamics analysis, and molecular dynamic simulation. The results showed that the lignin–EPTAC molecules formed a protective film on iron surface, resulting in an excellent inhibition efficiency of 97.80% at 100 mg/L concentration. The average surface roughness of steel samples was reduced to 26.6 nm from the original 99.3 nm. The adsorption of lignin–EPTAC molecules on the steel surface follows Langmuir adsorption isotherm model and was a physical–chemical process as well as an exothermic process of entropy reduction. This adsorption of lignin–EPTAC was a conjugated system dominated by benzene ring of lignin–EPTAC to form a chemical bond on the steel surface by conjugation, besides a positive interaction between the metal surface and the positively charged N ions in the head group of lignin–EPTAC.
Open Research
DATA AVAILABILITY STATEMENT
The raw data cannot be shared at this time due to time limitations.
Supporting Information
| Filename | Description |
|---|---|
| maco202011799-sup-0001-11799Supporting_information.docx770.5 KB | Supporting information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
REFERENCE
- 1J. Ding, B. Tang, M. Li, X. Feng, F. Fu, L. Bin, S. Huang, W. Su, D. Li, L. Zheng, J Clean Prod. 2017, 142, 2166.
- 2D. Yang, Y. Ye, Y. Su, S. Liu, D. Gong, H. Zhao, J Clean Prod. 2019, 229, 180.
- 3C. M. Fernandes, M. V. P. Mello, N. E. dos Santos, A. M. T. Souza, M. Lanznaster, E. A. Ponzio, Mater. Corros. 2019, 71, 280.
- 4W. Zhang, H.-J. Li, M. Wang, L.-J. Wang, A.-H. Zhang, Y.-C. Wu, New J. Chem. 2019, 43, 413.
- 5S. A. Umoren, A. A. AlAhmary, Z. M. Gasem, M. M. Solomon, Int. J. Biol. Macromol. 2018, 117, 1017.
- 6F. J. Rodriguez-Gomez, M. P. Valdelamar, A. E. Vazquez, P. D. Perez, R. Mata, A. Miralrio, M. Castro, J. Mol. Struct. 2019, 1183, 168.
- 7H. Lgaz, R. Salghi, S. Jodeh, B. Hammouti, J. Mol. Liq. 2017, 225, 271.
- 8R. S. Erami, M. Amirnasr, S. Meghdadi, M. Talebian, H. Farrokhpour, K. Raeissi, Corros. Sci. 2019, 151, 190.
- 9S. Yahya, N. K. Othman, M. C. Ismail, Eng. Fail. Anal. 2019, 100, 365.
- 10Y. Koumya, R. Idouhli, A. Sayout, A. Abouelfida, A. Benyaich, A. Romane, Metall. Mater. Trans. A 2019, 50A, 3002.
- 11M. A. Jafar Mazumder, RSC Adv. 2019, 9, 4277.
- 12N. Z. N. Hashim, E. Anouar, K. Kassim, H. M. Zaki, A. I. Alharthi, Z. Embong, Appl. Surf. Sci. 2019, 476, 861.
- 13Y. J. Qiang, S. T. Zhang, B. C. Tan, S. J. Chen, Corros. Sci. 2018, 133, 6.
- 14A. S. Fouda, M. A. Ismail, A. M. Temraz, A. S. Abousalem, New J. Chem. 2019, 43, 768.
- 15C. Gao, S. J. Wang, X. Y. Dong, K. Y. Liu, X. Zhao, F. G. Kong, Materials 2019, 12, 13.
- 16S. Dong, X. Yuan, S. Chen, L. Zhang, T. Huang, Ind. Eng. Chem. Res. 2018, 57, 13952.
- 17A. F. Szoke, G. S. Szabo, Z. Horvolgyi, E. Albert, L. Gaina, L. M. Muresan, Carbohydr. Polym. 2019, 215, 63.
- 18H. S. Su, Y. Liu, X. Gao, Y. F. Qian, W. J. Li, T. G. Ren, L. Wang, J. L. Zhang, J. Alloys Compd. 2019, 791, 681.
- 19G. L. F. Mendonca, S. N. Costa, V. N. Freire, P. N. S. Casciano, A. N. Correia, P. de Lima-Neto, Corros. Sci. 2017, 115, 41.
- 20X. H. Li, S. D. Deng, T. Lin, X. G. Xie, J. Mol. Liq. 2019, 282, 499.
- 21S. M. Elsaeed, E. S. H. El Tamany, H. Ashour, E. G. Zaki, E. A. Khamis, H. A. El Nagy, RSC Adv. 2018, 8, 37891.
- 22D. S. Chauhan, K. R. Ansari, A. A. Sorour, M. A. Quraishi, H. Lgaz, R. Salghi, Int. J. Biol. Macromol. 2018, 107, 1747.
- 23C. Wang, J. Chen, B. Hu, Z. Liu, C. Wang, J. Han, M. Su, Y. Li, C. Li, J. Clean Prod. 2019, 238, 117823.
- 24D. Liu, X. Qiu, M. Shao, J. Gao, J. Xu, Q. Liu, H. Zhou, Z. Wang, Mater. Corros. 2019, 70, 1907.
- 25A. Ehsani, M. G. Mahjani, M. Hosseini, R. Safari, R. Moshrefi, H. M. Shiri, J. Colloid Interface Sci. 2017, 490, 444.
- 26A. Dehghani, G. Bahlakeh, B. Ramezanzadeh, J. Mol. Liq. 2019, 282, 366.
- 27T. Gan, Y. Zhang, M. Yang, H. Hu, Z. Huang, Z. Feng, D. Chen, C. Chen, J. Liang, Ind. Eng. Chem. Res. 2018, 57, 10786.
- 28C. M. Fernandes, T. d S. Ferreira Fagundes, N. Escarpini dos Santos, T. Shewry de, M. Rocha, R. Garrett, R. M. Borges, G. Muricy, A. L. Valverde, E. A. Ponzio, Electrochim. Acta 2019, 312, 137.
- 29N. Asadi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, J. Taiwan Inst. Chem. 2019, 95, 252.
- 30F. Kong, K. Parhiala, S. Wang, P. Fatehi, Eur. Polym. J. 2015, 67, 335.
- 31T. Han, S. Ding, W. Yang, P. Jönsson, Chem. Eng. J. 2019, 373, 846.
- 32T. Lou, G. Cui, J. Xun, X. Wang, N. Feng, J. Zhang, Colloids Surf. Physicochem. Eng. Aspects 2018, 537, 149.
- 33Q. Wang, X. Pan, C. Lin, D. Lin, Y. Ni, L. Chen, L. Huang, S. Cao, X. Ma, Chem. Eng. J. 2019, 370, 1039.
- 34H. Y. Lu, X. F. Li, C. Q. Zhang, W. H. Li, D. P. Xu, Energy Source Part A. 2018, 41, 1716.
- 35A. Khadiri, R. Saddik, K. Bekkouche, A. Aouniti, B. Hammouti, N. Benchat, M. Bouachrine, R. Solmaz, J. Taiwan Inst. Chem. 2016, 58, 552.
- 36H. S. Maharana, P. K. Katiyar, K. Mondal, Appl. Surf. Sci. 2019, 478, 26.
- 37Y. Yan, W. Li, L. Cai, B. Hou, Electrochim. Acta. 2008, 53, 5953.
- 38I. B. Obot, D. D. Macdonald, Z. M. Gasem, Corros. Sci. 2015, 99, 1.
- 39R. Yan, W. He, T. Zhai, H. Ma, Electrochim. Acta 2019, 295, 942.
- 40M. Jokar, T. S. Farahani, B. Ramezanzadeh, J. Taiwan Inst. Chem. 2016, 63, 436.
- 41I. B. Obot, A. Madhankumar, Mater. Chem. Phys. 2016, 177, 266.
- 42J. Aljourani, K. Raeissi, M. A. Golozar, Corros. Sci. 2009, 51, 1836.
- 43Y. Sangeetha, S. Meenakshi, C. Sairam Sundaram, Carbohydr. Polym. 2016, 150, 13.
- 44S. A. Umoren, M. J. Banera, T. Alonso-Garcia, C. A. Gervasi, M. V. Mirífico, Cellulose 2013, 20, 2529.
- 45R. Macedo, N. D. N. Marques, J. Tonholo, R. C. Balaban, Carbohydr. Polym. 2019, 205, 371.
- 46J. Haque, V. Srivastava, C. Verma, H. Lgaz, R. Salghi, M. A. Quraishi, New J. Chem. 2017, 41, 13647.
- 47D. Q. Zhang, Y. M. Tang, S. J. Qi, D. W. Dong, H. Cang, G. Lu, Corros. Sci. 2016, 102, 517.
- 48L. O. Olasunkanmi, I. B. Obot, E. E. Ebenso, RSC Adv. 2016, 6, 86782.
