Volume 69, Issue 7 pp. 1079-1087

ARTICLE

Novel Gd₂O₃/SrFe₁₂O₁₉@Schiff base chitosan (Gd/SrFe@SBCs) nanocomposite as a novel magnetic sorbent for the removal of Pb(II) and Cd(II) ions from aqueous solution

Saade Abdalkareem Jasim,

Saade Abdalkareem Jasim

Medical Laboratory Techniques Department, Al-Maarif University College, Ramadi, Iraq

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Walid Kamal Abdelbasset,

Corresponding Author

Walid Kamal Abdelbasset

[email protected]

Department of Health and Rehabilitation Sciences, College of Applied Medical Sciences, Prince Sattam bin Abdulaziz University, Al Kharj, Saudi Arabia

Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt

Correspondence

Walid Kamal Abdelbasset, Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt.

Email: [email protected] (W.K.A.)

Mustafa M. Kadhim, Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq.

Email: [email protected] (M.M.K.)

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Kadda Hachem,

Kadda Hachem

orcid.org/0000-0003-2683-0101

Laboratory of Biotoxicology, Pharmacognosy and Biological Valorization of Plants (LBPVBP), Faculty of Sciences, University of Saida - Dr Moulay Tahar, Saïda, Algeria

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Mustafa M. Kadhim,

Corresponding Author

Mustafa M. Kadhim

[email protected]

Department of Dentistry, Kut University College, Kut, Iraq

College of Technical Engineering, The Islamic University, Najaf, Iraq

Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq

Correspondence

Walid Kamal Abdelbasset, Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt.

Email: [email protected] (W.K.A.)

Mustafa M. Kadhim, Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq.

Email: [email protected] (M.M.K.)

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Ghulam Yasin,

Ghulam Yasin

Department of Botany, Bahauddin Zakariya University, Multan, Pakistan

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Maithm A. Obaid,

Maithm A. Obaid

National University of Science and Technology, College of Pharmacy, Thi Qar, Iraq

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Baydaa Abed Hussein,

Baydaa Abed Hussein

Department of Biology, Al-Manara College for Medical Sciences, Misan, Iraq

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Holya A. Lafta,

Holya A. Lafta

Department of Physics, Al-Nisour University College, Baghdad, Iraq

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Yasser Fakri Mustafa,

Yasser Fakri Mustafa

Department of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul, Iraq

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Zaid Hameed Mahmoud,

Zaid Hameed Mahmoud

Department of Chemistry, Diyala University, College of Science, Baqubah, Iraq

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Saade Abdalkareem Jasim,

Saade Abdalkareem Jasim

Medical Laboratory Techniques Department, Al-Maarif University College, Ramadi, Iraq

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Walid Kamal Abdelbasset,

Corresponding Author

Walid Kamal Abdelbasset

[email protected]

Department of Health and Rehabilitation Sciences, College of Applied Medical Sciences, Prince Sattam bin Abdulaziz University, Al Kharj, Saudi Arabia

Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt

Correspondence

Walid Kamal Abdelbasset, Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt.

Email: [email protected] (W.K.A.)

Mustafa M. Kadhim, Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq.

Email: [email protected] (M.M.K.)

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Kadda Hachem,

Kadda Hachem

orcid.org/0000-0003-2683-0101

Laboratory of Biotoxicology, Pharmacognosy and Biological Valorization of Plants (LBPVBP), Faculty of Sciences, University of Saida - Dr Moulay Tahar, Saïda, Algeria

Search for more papers by this author

Mustafa M. Kadhim,

Corresponding Author

Mustafa M. Kadhim

[email protected]

Department of Dentistry, Kut University College, Kut, Iraq

College of Technical Engineering, The Islamic University, Najaf, Iraq

Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq

Correspondence

Walid Kamal Abdelbasset, Department of Physical Therapy, Kasr Al-Aini Hospital, Cairo University, Giza, Egypt.

Email: [email protected] (W.K.A.)

Mustafa M. Kadhim, Department of Pharmacy, Osol Aldeen University College, Baghdad, Iraq.

Email: [email protected] (M.M.K.)

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Ghulam Yasin,

Ghulam Yasin

Department of Botany, Bahauddin Zakariya University, Multan, Pakistan

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Maithm A. Obaid,

Maithm A. Obaid

National University of Science and Technology, College of Pharmacy, Thi Qar, Iraq

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Baydaa Abed Hussein,

Baydaa Abed Hussein

Department of Biology, Al-Manara College for Medical Sciences, Misan, Iraq

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Holya A. Lafta,

Holya A. Lafta

Department of Physics, Al-Nisour University College, Baghdad, Iraq

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Yasser Fakri Mustafa,

Yasser Fakri Mustafa

Department of Pharmaceutical Chemistry, College of Pharmacy, University of Mosul, Mosul, Iraq

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Zaid Hameed Mahmoud,

Zaid Hameed Mahmoud

Department of Chemistry, Diyala University, College of Science, Baqubah, Iraq

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First published: 11 July 2022

https://doi.org/10.1002/jccs.202200013

Citations: 3

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Abstract

In this work, novel Gd₂O₃/SrFe₁₂O₁₉@Schiff base chitosan (Gd/SrFe@SBCs) nanocomposite was prepared, and characterized using FT-IR, XRD, DSC, VSM, FE-SEM, X-ray energy dispersive spectrum (EDS), and map analyses. All results confirm that the Gd₂O₃/SrFe₁₂O₁₉ nanocomposite/Schiff base chitosan was successfully prepared. EDS and map analyses predict that all elements are well distributed to the compound. VSM shows that the title compound has high saturation magnetic of 17.35 emu/g with high coercivity of 4,664 Oe. In addition, Gd/SrFe@SBCs were used as new adsorbents to the removal of Pb(II) and Cd(II) ions from aqueous solution, and results confirm that the removal efficiency of Pb(II) (98%) is higher than Cd(II) (78%) ion. At best conditions, the maximum adsorption capacity for Pb(II) is 183.7 and for Cd(II) is 146.2 mg/g. Reusability results show that the adsorption efficiency of Gd/SrFe@SBCs remained above 93% for Pb(II) and 71% for Cd(II) after five adsorption/desorption cycles. The effect of coexisting cation and anions was studied and confirm that the Gd/SrFe@SBCs had selective adsorption toward Pb(II). According to these results, we proposed that Gd/SrFe@SBCs studied as a sorbent to removal of other heavy metal ions.

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Volume69, Issue7

July 2022

Pages 1079-1087

Novel Gd₂O₃/SrFe₁₂O₁₉@Schiff base chitosan (Gd/SrFe@SBCs) nanocomposite as a novel magnetic sorbent for the removal of Pb(II) and Cd(II) ions from aqueous solution

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Novel Gd2O3/SrFe12O19@Schiff base chitosan (Gd/SrFe@SBCs) nanocomposite as a novel magnetic sorbent for the removal of Pb(II) and Cd(II) ions from aqueous solution

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Novel Gd₂O₃/SrFe₁₂O₁₉@Schiff base chitosan (Gd/SrFe@SBCs) nanocomposite as a novel magnetic sorbent for the removal of Pb(II) and Cd(II) ions from aqueous solution