Supported Atomically Dispersed Pd Catalyzed Direct Alkoxylation and Allylic Alkylation†
Corresponding Author
Ruixuan Qin
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan, Fujian, 366300 China
E-mail: [email protected]; [email protected]Search for more papers by this authorZiwen Chen
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210 China
Search for more papers by this authorQingyuan Wu
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Search for more papers by this authorNanfeng Zheng
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan, Fujian, 366300 China
Search for more papers by this authorCorresponding Author
Pengxin Liu
School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210 China
E-mail: [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Ruixuan Qin
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan, Fujian, 366300 China
E-mail: [email protected]; [email protected]Search for more papers by this authorZiwen Chen
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210 China
Search for more papers by this authorQingyuan Wu
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Search for more papers by this authorNanfeng Zheng
New Cornerstone Science Laboratory, State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and National & Local Joint Engineering Research Center of Preparation Technology of Nanomaterials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen, Fujian, 361102 China
Fujian Key Laboratory of Rare-earth Functional Materials, Fujian Shanhai Collaborative Innovation Center of Rare-earth Functional Materials, Longyan, Fujian, 366300 China
Search for more papers by this authorCorresponding Author
Pengxin Liu
School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210 China
E-mail: [email protected]; [email protected]Search for more papers by this authorDedicated to the Special Issue of Single-Atom Catalysis.
Comprehensive Summary
A new approach to allylic alkylation is realized using an atomically dispersed palladium catalyst (Pd1/TiO2-EG). Unlike conventional methods that require derivation of substrates and utilization of additives, this method allows for direct allylic alkylation from allylic alcohols, producing H2O as the sole by-product. The catalyst's high efficiency is attributed to the local hydrogen bonding at the organic-inorganic interface (Pd-EG interface), facilitating hydroxyl group activation for η3 π-allyl complex formation. The system demonstrates successful direct C—O and C—C coupling reactions with high selectivity, requiring no additives. This study highlights the potential of supported atomically dispersed catalysts for greener and more efficient catalysis, meanwhile, offers unique insights into the distinct behavior of atomically dispersed catalysts in comparison to homogeneous or nanoparticle-based catalysts.
Supporting Information
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Appendix S1: Supporting Information |
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