A Pyrazine-Based 2D Conductive Metal-Organic Framework for Efficient Lithium Storage†
Xiaoxiao Sun
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorCorresponding Author
Xiaoli Yan
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorKeming Song
College of Chemistry and Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001 China
Search for more papers by this authorTing Zhang
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorZongfan Yang
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorXi Su
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorCorresponding Author
Weihua Chen
College of Chemistry and Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Long Chen
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorXiaoxiao Sun
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorCorresponding Author
Xiaoli Yan
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorKeming Song
College of Chemistry and Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001 China
Search for more papers by this authorTing Zhang
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorZongfan Yang
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorXi Su
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
Search for more papers by this authorCorresponding Author
Weihua Chen
College of Chemistry and Green Catalysis Center, Zhengzhou University, Zhengzhou, Henan, 450001 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorCorresponding Author
Long Chen
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, Tianjin University, Tianjin, 300072 China
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, Jilin, 130012 China
E-mail: [email protected]; [email protected]; [email protected]Search for more papers by this authorDedicated to the Special Issue of Optoelectronic Functional Materials.
Comprehensive Summary
The merits of intrinsic electrical conductivity, high specific surface area, tunable chemical composition and tailor-made properties enable two-dimensional conductive metal-organic frameworks (2D c-MOFs) as promising next-generation electrode materials in the field of energy storage and conversion. Herein, we have designed and synthesized a novel pyrazine-based 2D c-MOF (TPQG-Cu-MOF) bearing extended π-conjugated structure and abundant redox active sites. Thanks to the excellent redox reversibility of pyrazine units and CuO2 units, as well as the insolubility of the rigid framework skeleton, TPQG-Cu-MOF as the cathode material of lithium-ion battery exhibits a reversible specific capacity (150.2 mAh·g–1 at 20 mAh·g–1), good cycling stability (capacity retention of 82.6% after 500 cycles at 1 A·g–1) and excellent rate performance. Comprehensive ex-situ spectroscopic studies revealed the reversible redox activity of pyrazine units and CuO2 units of TPQG-Cu-MOF during the Li+ insertion/extraction process. The deepening fundamental understanding of the structure-property relationship was proposed, which might pave the way for further development of efficient MOF-based energy storage devices.
Supporting Information
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Citing Literature
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