Cu(OAc)2-Mediated Synthesis of Fullerodihydropyridine-3-ones via the Reaction of [60]Fullerene with β-Substituted Ethylamines in the Absence or Presence of Arylacetaldehydes†
Xiu-Shan Liu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorHui-Juan Wang
State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, Hubei, 430071 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorFei-Lun Wu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorJing-Wen Huo
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorXing-Yu Wang
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorCorresponding Author
Fa-Bao Li
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, Hubei, 430062 China
E-mail: [email protected]; [email protected]Search for more papers by this authorRui Sun
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorLi Liu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorCorresponding Author
Chao-Yang Liu
State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, Hubei, 430071 China
E-mail: [email protected]; [email protected]Search for more papers by this authorXiu-Shan Liu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorHui-Juan Wang
State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, Hubei, 430071 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorFei-Lun Wu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
‡ These authors contributed equally to this work.
† Dedicated to the Special Issue of Recent Advances in Fullerene Chemistry.
Search for more papers by this authorJing-Wen Huo
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorXing-Yu Wang
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorCorresponding Author
Fa-Bao Li
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, Hubei, 430062 China
E-mail: [email protected]; [email protected]Search for more papers by this authorRui Sun
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorLi Liu
State Key Laboratory of Biocatalysis and Enzyme Engineering, School of Life Sciences, Hubei University, Wuhan, Hubei, 430062 China
Search for more papers by this authorCorresponding Author
Chao-Yang Liu
State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Center for Magnetic Resonance, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, Hubei, 430071 China
E-mail: [email protected]; [email protected]Search for more papers by this authorComprehensive Summary
A series of unreported fullerodihydropyridine-3-ones were synthesized as a new family of fullerene derivatives in moderate to good yields by a simple one-step reaction of [60]fullerene with cheap and readily available β-substituted ethylamines in the absence or presence of arylacetaldehydes under the assistance of Cu(OAc)2. The in situ generation of arylacetaldehydes by the C—N bond cleavage of arylethylamines avoided their complex synthesis in advance and realized the preparation of fullerodihydropyridine-3-ones with structural and functional diversities, which may have promising applications in perovskite solar cells to improve the performance of photovoltaic devices due to the existence of a large π-conjugated system on the dihydropyridine-3-one ring.
Supporting Information
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Appendix S1: Supporting Information |
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