Octanuclear Palladacycles with B(3)–H Bond Activation of o-Carborane†
Run-Ze Yuan
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorPeng-Fei Cui
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorYue-Jian Lin
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorCorresponding Author
Guo-Xin Jin
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
E-mail: [email protected]Search for more papers by this authorRun-Ze Yuan
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorPeng-Fei Cui
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorYue-Jian Lin
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
Search for more papers by this authorCorresponding Author
Guo-Xin Jin
State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433 China
E-mail: [email protected]Search for more papers by this authorDedicated to Professor Erkang Wang on the occasion of his 90th Birthday.
Comprehensive Summary
Herein, we describe the synthesis of a carborane-supported octanuclear palladacycle complex, Pd8(o-C2B10H10CS2CH3)4Cl4(CH3CN)4 (complex 1), with B(3)–H activations on o-carborane ligand. The substitution reaction of 1 has been explored, and three of its substituted complexes Pd8(o-C2B10H10CS2CH3)4Cl4(L)4 (L = tBuNC, 2; L = C5H5N, 3; L = C4H8S, 4) have been synthesized. The m- and p-carborane disubstituted ligands m- and p-C2B10H10(CS2CH3)2 (ligands 5 and 6) as well as their B—H activated carborane complexes [m-C2B10H9(CS2CH3)2PdCl] (7) and [p-C2B10H8(CS2CH3)2][PdCl(tBuNC)]2 (8) have also been synthesized by the similar method. All of these complexes have been characterized, including X-ray single crystal diffraction, NMR spectroscopy, IR spectroscopy and elemental analysis methods.
Supporting Information
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Citing Literature
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