Preparation, Crystal Structure and Properties of a New Crystal Form of Diammonium 5,5′-bistetrazole-1,1′-diolate
Xiaojun Wang
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Research Institute of Gansu Yin Guang Chemical Industry Group, Baiyin, Gansu 730900, China
Search for more papers by this authorShaohua Jin
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorChunyuan Zhang
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorLijie Li
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorShusen Chen
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorCorresponding Author
Qinghai Shu
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China, Tel.: 0086-010-68915072; Fax: 0086-010-68918535Search for more papers by this authorXiaojun Wang
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Research Institute of Gansu Yin Guang Chemical Industry Group, Baiyin, Gansu 730900, China
Search for more papers by this authorShaohua Jin
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorChunyuan Zhang
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorLijie Li
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorShusen Chen
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Search for more papers by this authorCorresponding Author
Qinghai Shu
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China, Tel.: 0086-010-68915072; Fax: 0086-010-68918535Search for more papers by this authorAbstract
A new crystal form of diammonium 5,5′-bistetrazole-1,1′-diolate (1) was prepared by two novel methods and fully characterized by using IR, NMR spectroscopy, elementary analysis, single crystal X-ray crystallography and thermal gravity/differential thermal analysis (TG/DTA). Crystalline 1 was found as monoclinic and space group of P21/c (14). The TG/DTA analysis showed that the decomposition temperature of 1 was 287.8°C with a mass loss of 91.2% in the range of 220–300°C at a heating rate of 5°C/min. The sensitivities test towards impact, friction of 1 indicated that 1 has much lower sensitivities than those of RDX/HMX and is comparable to those of TNT, which suggested that 1 could be used as a good candidate of new insensitive energetic compound.
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