Recent Progress in the Synthesis and Application of Saddle-shaped Cyclooctatetrathiophenes and Their Derivatives
Chunmei Zhao
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006, China
Search for more papers by this authorLi Xu
College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorYong Wang
College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorChunli Li
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorCorresponding Author
Hua Wang
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China, Tel.: 0086-0371-23897112; Fax: 0086-0371-3881358Search for more papers by this authorChunmei Zhao
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006, China
Search for more papers by this authorLi Xu
College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorYong Wang
College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorChunli Li
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Search for more papers by this authorCorresponding Author
Hua Wang
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China
Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, Henan 475004, China, Tel.: 0086-0371-23897112; Fax: 0086-0371-3881358Search for more papers by this authorAbstract
Cyclooctatetrathiophene (COTh) shows a novel saddle-shaped molecular structure, which has been applied in organic synthesis and material science. In this paper, the design and synthesis of COThs and their derivatives were described. The derivatives of COThs include mainly four types. One is isomer with different sequences of the four thiophene rings; the second is oligomer such as dimmer and dendrimer; the third is derivative functionalized by substituent groups at the four α positions; the last is the one planarized by sulfur, silicon or sulfone bridges. The applications of COThs and their derivatives in molecular muscles and field effect transistors were also discussed.
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