Three-Component Cucurbit[6]uril Framework with 1:2 Host-Guest Motif and Dimeric Boric Acid
Meng Wang
Dalian University of Technology, Dalian, Liaoning 116024, China
Search for more papers by this authorXiang Li
Dalian University of Technology, Dalian, Liaoning 116024, China
Search for more papers by this authorCorresponding Author
Li Liu
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China, Tel.: 0086-0411-84379903Search for more papers by this authorMeng Wang
Dalian University of Technology, Dalian, Liaoning 116024, China
Search for more papers by this authorXiang Li
Dalian University of Technology, Dalian, Liaoning 116024, China
Search for more papers by this authorCorresponding Author
Li Liu
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China, Tel.: 0086-0411-84379903Search for more papers by this authorAbstract
Three-component framework of cucurbit[6]uril, 3-(1-methylimidazolium-3-yl)propane-1-sulfonate and boric acid has been constructed. The crystal structure reveals 1:2 host-guest motif of cucurbit[6]uril and 3-(1-methyl-imidazolium-3-yl)propane-1-sulfonate, demonstrating both cation binding of imidazolium moiety and anion binding of sulfonate moiety for the first time. Incorporation of dimeric boric acid facilitates the formation of metal-free three-dimensional framework.
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