Synthesis and Structural Characterization of a New 2D Coordination Polymer [Cu(pzta)2]n
Cong LIU
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorYongjiang WANG
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorJixi GUO
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorCong LIU
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorYongjiang WANG
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorJixi GUO
College of Life Science & Chemistry, Xinjiang Normal University, Urumqi, Xinjiang 830054, China
Search for more papers by this authorAbstract
A new copper(II) tetrazolate coordination polymer [Cu(pzta)2]n (1) (pzta=5-pyrazinyltetrazolate) was prepared from the hydrothermal reaction of Cu(OAc)2·H2O with NaN3 and pyrazinecarbonitrile (pzCN) in the presence of ethanol, and characterized by elemental analysis, IR, TGA and X-ray crystallography. The X-ray diffraction analysis of 1 shows that the compound crystallizes in the monoclinic system with space group P2(1)/c and Cu(II) ion center is six-coordinated by four different pzta ligands. The complex 1 features a 2D tetrazole coordination polymer. The thermal analysis of 1 shows that the decomposition of the complex occurs in two regions.
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