Micro-Macroporous Composite Materials: SiC Ceramic Foams Functionalized With the Metal Organic Framework HKUST-1
Ulf Betke
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorSteven Proemmel
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorJakob G. Eggebrecht
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorStefan Rannabauer
Otto-von-Guericke-University Magdeburg, Institute for Materials and Joining Technology – Nonmetallic Materials, Große Steinernetischstraße 6, 39104 Magdeburg, Germany.
Search for more papers by this authorCorresponding Author
Alexandra Lieb
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, GermanySearch for more papers by this authorMichael Scheffler
Otto-von-Guericke-University Magdeburg, Institute for Materials and Joining Technology – Nonmetallic Materials, Große Steinernetischstraße 6, 39104 Magdeburg, Germany.
Search for more papers by this authorFranziska Scheffler
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorUlf Betke
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorSteven Proemmel
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorJakob G. Eggebrecht
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorStefan Rannabauer
Otto-von-Guericke-University Magdeburg, Institute for Materials and Joining Technology – Nonmetallic Materials, Große Steinernetischstraße 6, 39104 Magdeburg, Germany.
Search for more papers by this authorCorresponding Author
Alexandra Lieb
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, GermanySearch for more papers by this authorMichael Scheffler
Otto-von-Guericke-University Magdeburg, Institute for Materials and Joining Technology – Nonmetallic Materials, Große Steinernetischstraße 6, 39104 Magdeburg, Germany.
Search for more papers by this authorFranziska Scheffler
Otto-von-Guericke-University Magdeburg, Chemical Institute – Industrial Chemistry, Universitätsplatz 2, 39106 Magdeburg, Germany
Search for more papers by this authorAbstract
The metal organic framework material Cu3(btc)2·3H2O (HKUST-1) was grown on differently activated oxide-bonded SiC ceramic foams with varying pore sizes. Activation was performed by an alkaline etching procedure under dissolution of the SiO2 binder phase in the ob-SiC microstructure leading to an increase in strut surface roughness. The influence of foam pore size, etching conditions (duration, temperature) and the effect of a subsequent alumina coating to increase the coverage with –OH moieties was studied. The activated foams and MOF@ob-SiC composites were characterized by microstructural analysis, H2O adsorption and thermal conductivity measurements.
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