Crystallization and Purification of 4,4′-Diaminodiphenyl Ether
Corresponding Author
Jianxin Chen
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Hebei University of Technology, National-Local Joint Engineering Laboratory for Energy Conservation of Chemical Process Integration and Resources Utilization, 300130 Tianjin, China
Correspondence: Jianxin Chen ([email protected]), School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China; Qing Wu ([email protected]), School of Artificial Intelligence, Hebei University of Technology, Tianjin, 300130, China.Search for more papers by this authorFengjiang Chen
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorJian Han
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorMin Su
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorKaili Liu
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorYinhui Li
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorCorresponding Author
Qing Wu
Hebei University of Technology, School of Artificial Intelligence, 300130 Tianjin, China
Correspondence: Jianxin Chen ([email protected]), School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China; Qing Wu ([email protected]), School of Artificial Intelligence, Hebei University of Technology, Tianjin, 300130, China.Search for more papers by this authorCorresponding Author
Jianxin Chen
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Hebei University of Technology, National-Local Joint Engineering Laboratory for Energy Conservation of Chemical Process Integration and Resources Utilization, 300130 Tianjin, China
Correspondence: Jianxin Chen ([email protected]), School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China; Qing Wu ([email protected]), School of Artificial Intelligence, Hebei University of Technology, Tianjin, 300130, China.Search for more papers by this authorFengjiang Chen
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorJian Han
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorMin Su
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorKaili Liu
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorYinhui Li
Hebei University of Technology, School of Chemical Engineering and Technology, 300130 Tianjin, China
Search for more papers by this authorCorresponding Author
Qing Wu
Hebei University of Technology, School of Artificial Intelligence, 300130 Tianjin, China
Correspondence: Jianxin Chen ([email protected]), School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China; Qing Wu ([email protected]), School of Artificial Intelligence, Hebei University of Technology, Tianjin, 300130, China.Search for more papers by this authorAbstract
The purification of 4,4′-diaminodiphenyl ether (ODA) was investigated. ODA, which contained impurities, was sublimated and anti-solvent (ethanol)-crystallized in N-dimethylformamide (DMF). Fourier transform infrared (FTIR) results revealed that the sublimated crystal was basically identical with the pure ODA sample. The influence of different amounts of ethanol on particle size distribution was analyzed during anti-solvent crystallization. The morphology of the ODA crystal was examined by scanning electron microscopy (SEM). The color of the sample enhanced from a brown powder to a colorless granular crystal. The purity of the sample could be increased from about 30 % to 87 %. With the operations of sublimation and anti-solvent crystallization, the purity, crystal morphology, and particle size distribution of ODA were significantly improved.
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