A Comparative Study of Hydroxyapatite- and Alumina-Based Catalysts in Dry Reforming of Methane
Bruna Rego de Vasconcelos
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Université de Sherbrooke, Biomass Technology Laboratory, Department of Chemical and Biotechnological Engineering, J1K 2R1 Sherbrooke, Québec, Canada
Search for more papers by this authorCorresponding Author
Doan Pham Minh
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Duy Tan University, Institute of Research and Development, 550000 Da Nang, Vietnam
Correspondence: Doan Pham Minh ([email protected]), Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France.Search for more papers by this authorEmmanuel Martins
PRAYON S.A., rue J. Wauters, 144, 4480 Engis, Belgium
Search for more papers by this authorAlain Germeau
PRAYON S.A., rue J. Wauters, 144, 4480 Engis, Belgium
Search for more papers by this authorPatrick Sharrock
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Search for more papers by this authorAnge Nzihou
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Search for more papers by this authorBruna Rego de Vasconcelos
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Université de Sherbrooke, Biomass Technology Laboratory, Department of Chemical and Biotechnological Engineering, J1K 2R1 Sherbrooke, Québec, Canada
Search for more papers by this authorCorresponding Author
Doan Pham Minh
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Duy Tan University, Institute of Research and Development, 550000 Da Nang, Vietnam
Correspondence: Doan Pham Minh ([email protected]), Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France.Search for more papers by this authorEmmanuel Martins
PRAYON S.A., rue J. Wauters, 144, 4480 Engis, Belgium
Search for more papers by this authorAlain Germeau
PRAYON S.A., rue J. Wauters, 144, 4480 Engis, Belgium
Search for more papers by this authorPatrick Sharrock
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Search for more papers by this authorAnge Nzihou
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE, Campus Jarlard, 81013 Albi cedex 09, France
Search for more papers by this authorAbstract
The dry reforming of methane over hydroxyapatite- and alumina/magnesia (commercial Pural MG 30)-supported nickel catalysts was investigated. The catalytic performance of the catalysts prepared with fresh supports highly depended on the basicity, the metal-support interaction, and the metal particle size. Calcination of the supports at 1200 °C for 5 h made the catalysts less active because of specific surface area reduction and basicity destruction. However, this treatment allowed avoiding any further catalyst deactivation by thermal sintering and maintained excellent catalytic stability over 300 h of time-on-stream. These tests under simulated industrial conditions (high contact time and long time-on-stream) showed the competitiveness of the prepared catalysts in this important catalytic process.
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