Isothermal Adsorption Behavior of Cesium Ions in a Novel Chitosan-Prussian Blue-Based Membrane
Tomoyuki Fujisaki
National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, 323-0806 Oyama, Tochigi, Japan
Search for more papers by this authorCorresponding Author
Keita Kashima
National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, 323-0806 Oyama, Tochigi, Japan
Correspondence: Keita Kashima ([email protected]), National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, Oyama, Tochigi, 323-0806, Japan.Search for more papers by this authorMasahide Hagiri
National Institute of Technology, Fukushima College, Department of Applied Chemistry and Biochemistry, 30 Nagao, Kamiarakawa, Taira, Iwaki, 970-8034 Fukushima, Japan
Search for more papers by this authorMasanao Imai
Nihon University, Graduate School of Bioresource Sciences, 1866, Kameino, Fujisawa, 252-0880 Kanagawa, Japan
Search for more papers by this authorTomoyuki Fujisaki
National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, 323-0806 Oyama, Tochigi, Japan
Search for more papers by this authorCorresponding Author
Keita Kashima
National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, 323-0806 Oyama, Tochigi, Japan
Correspondence: Keita Kashima ([email protected]), National Institute of Technology, Oyama College, Department of Materials Chemistry and Bioengineering, 771 Ohaza-Nakakuki, Oyama, Tochigi, 323-0806, Japan.Search for more papers by this authorMasahide Hagiri
National Institute of Technology, Fukushima College, Department of Applied Chemistry and Biochemistry, 30 Nagao, Kamiarakawa, Taira, Iwaki, 970-8034 Fukushima, Japan
Search for more papers by this authorMasanao Imai
Nihon University, Graduate School of Bioresource Sciences, 1866, Kameino, Fujisawa, 252-0880 Kanagawa, Japan
Search for more papers by this authorAbstract
Prussian blue (PB) particles were successfully immobilized on a novel chitosan membrane. Morphological observations confirmed that the PB particles were densely immobilized within the membrane. From isothermal adsorption analysis, an increase in the mass fraction of PB contained within the membrane (MFPB) assisted the improvement of the initial adsorption rate as well as the adsorption uptake of cesium ions. A high MFPB led to a decrease in the effective diffusion coefficient of cesium ions in the membrane. Adsorption equilibrium data were found in good agreement with the Langmuir model. The maximum adsorption capacity of the membrane immobilizing PB as well as the adsorption constant in the Langmuir model increased with higher MFPB.
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