Research Article
Detection of Microscale Mass-Transport Regimes in Supercritical Fluid Extraction
Arthur A. Salamatin,
Corresponding Author
Arthur A. Salamatin
Kazan Federal University, Department of Aerohydromechanics, Kremlyovskaya Str. 18, 420008 Kazan, Russia
Correspondence: Arthur A. Salamatin ([email protected]), Kazan Federal University, Department of Aerohydromechanics, Kremlyovskaya Str. 18, Kazan, 420008, Russia.Search for more papers by this authorArthur A. Salamatin,
Corresponding Author
Arthur A. Salamatin
Kazan Federal University, Department of Aerohydromechanics, Kremlyovskaya Str. 18, 420008 Kazan, Russia
Correspondence: Arthur A. Salamatin ([email protected]), Kazan Federal University, Department of Aerohydromechanics, Kremlyovskaya Str. 18, Kazan, 420008, Russia.Search for more papers by this authorAbstract
The problem of detecting supercritical fluid extraction regimes on the particle-scale level is discussed by using a generalized multiparameter model, which includes the shrinking-core (SC) and broken-and-intact-cells (BIC) approaches as its limiting cases. The model accounts for two internal mass-transfer resistances attributed to cell membranes and transport channels. A wide spectrum of particle-scale extraction regimes, described by the model, agree with available up-to-date relatively short laboratory experiments. Simplified concepts (like SC or BIC) could only be used for available experimental data correlation, and do not allow a reliable extension to long process times. The experimental methodology was suggested to detect limiting internal mass-transfer mechanisms.
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