Research Article
Heterogeneous Reactor Modeling of an Industrial Multitubular Packed-Bed Ethylene Oxide Reactor
Zeeshan Nawaz,
Corresponding Author
Zeeshan Nawaz
SABIC Technology & Innovation, Saudi Basic Industries Corporation (SABIC), Riyadh, Kingdom of Saudi Arabia.
SABIC Technology & Innovation, Saudi Basic Industries Corporation (SABIC), Riyadh, Kingdom of Saudi Arabia.Search for more papers by this authorZeeshan Nawaz,
Corresponding Author
Zeeshan Nawaz
SABIC Technology & Innovation, Saudi Basic Industries Corporation (SABIC), Riyadh, Kingdom of Saudi Arabia.
SABIC Technology & Innovation, Saudi Basic Industries Corporation (SABIC), Riyadh, Kingdom of Saudi Arabia.Search for more papers by this authorAbstract
The one-dimensional heterogeneous model of an industrial multitubular packed-bed ethylene oxide (EO) reactor was developed using the equation-oriented platform Aspen Custom Modeler. Reactor operation was optimized in terms of maximized EO production and selectivity and enhanced safety related to the presence of oxygen in the EO reactor. Good agreement was found between the model results during validation against the available information under identical operating conditions. The model predicts the behavior of the EO reaction and demonstrates the extent of catalyst utilization with product distribution, product yield, by-product formation, temperature and concentration profiles, over time and along the length of the reactor or catalyst bed. The model sensitivity studies compute the optimum feed flow, oxygen concentration, feed pressure, etc. and suggest the best operational philosophy.
References
- 1 S. Rebsdat, D. Mayer, in Ullmann's Encylopedia of Industrial Chemistry, Wiley-VCH, Weinheim 2012.
- 2 C. Hirose, Bull. Chem. Soc. Jpn. 1974, 47 (6), 1311–1318.
- 3
A. Wurtz, Justus Liebigs Ann. Chem. 1859, 110, 125–128.
10.1002/jlac.18591100116 Google Scholar
- 4 A. Kursawe, Ph.D. Thesis, Technical University Chemnitz 2009.
- 5 T. E. Lefort, (Société Française de Catalyse Generale), FR 729952, 1931.
- 6 T. E. Lefort, (Société Française de Catalyse Generale), FR 739562, 1931.
- 7 X.-G. Zhou, W. K. Yuan, Chem. Eng. Process. 2005, 44 (10), 1098–1107.
- 8 S. Hwang, R. Smith, Chem. Eng. Sci. 2004, 59 (20), 4229–4243.
- 9 C. Avi, Indian Chem. Eng. 2006, 48 (3), 1–7.
- 10
S. Aryana, M. Ahmadi, V. Gomes, J. Romagnoli, K. Ngian, Chem. Prod. Process Model. 2009, 4 (1), 14. DOI: 10.2202/1934-2659.1231
10.2202/1934‐2659.1231 Google Scholar
- 11 S. K. Lahiri, N. Khalfe, Can. J. Chem. Eng. 2009, 87 (1), 118–128.
- 12 N. Rezaie, A. Jahanmiri, B. Moghtaderi, M. R. Rahimpour, Chem. Eng. Process. 2005, 44 (8), 911–921.
- 13 M. R. Rahimpour, M. Shayanmehr, M. Nazari, Ind. Eng. Chem. Res. 2011, 50 (10), 6044–6052.
- 14 H. C. Schultze, Glycols (Eds: G. O. Curme), Reinhold Publishing, New York 1952, 74–113.
- 15 B. J. Ozero, J. V. Procelli, Hydrocarbon Process. 1984, 63 (3), 55–61.
- 16 DWE Reactor for Production of Ethylene Oxide (EO), http://dwe.man.eu/chemical-reactors/tubular-reactors-with-air-oil-boiling-and-pressure-water-cooling/ethylene-oxide-(eo) (Accessed on October 01, 2015)
- 17 J. Huang, D. Resendez, G. Tran, Ethylene Oxide Reactor System, 1999. www.owlnet.rice.edu/∼ceng403/gr1599/finalreport3.html (Accessed on August 14, 2015)
- 18 Ullmann's Encyclopaedia of Industrial Chemistry, 5th ed., Vol. A10, Wiley-VCH, Weinheim 1987, 117–135.
- 19 J. C. Zomerdijk, M. W. Hall, Catal. Rev.: Sci. Eng. 1981, 23 (1–2), 163–185.
- 20 K. Dialer, Chem. Ing. Tech. 1982, 54 (1), 18.
- 21 T. E. Corrigan, Pet. Refin. 1933, 32 (2), 87.
- 22 Scientific Design's Ethylene Oxide/Ethylene Glycol (EO/EG) technology, www.scidesign.com/technologies/ethylene-oxide-and-derivatives/ethylene-oxide-ethylene-glycols (Accessed on October 01, 2015)
- 23 G. Zahedi, A. Lohib, K. A. Mahdic, Fuel Process. Technol. 2011, 92 (9), 1725–1732.
- 24 J. Coombs, D. Kim, L. Palombo, Celanese Clearlake Ethylene Oxide Reactor Revamp, JChem Inc., 1997. www.owlnet.rice.edu/∼ceng403/ethox97.html (Accessed on October 01, 2015)
- 25 B. J. Ozero, S. D. Becker, US Patent 4921681, 1990.
- 26 A. A. Iordanidis, Ph.D. Thesis, University of Twente 2002.
- 27
O. Galan, V. G. Gomes, J. Romagnoli, K. F. Ngian, Int. J. Chem. React. Eng. 2009, 7, A32. DOI: 10.2202/1542-6580.2058
10.2202/1542‐6580.2058 Google Scholar
- 28 B. Crudge, B. Billig, R. Schneider, Hydrocarbon Process. 2011. www.hydrocarbonprocessing.com/Article/2941980/Optimize-capacity-for-large-ethylene-oxide-reactors.html
- 29 M. M. Tirtowidjojo, C. Zarth, S. Sen, P. D. Patil, WO 2011116157 A1, 2011.
- 30
A. Vandervoort, J. Thibault, Y. P. Gupta, Int. J. Chem. React. Eng. 2011, 9, A81. DOI: 10.1515/1542-6580.2548
10.1515/1542‐6580.2548 Google Scholar
- 31 N. Piccinini, G. Levy, Can. J. Chem. Eng. 1984, 62 (4), 541–546.
- 32 G. Groppi, E. Tronconi, Catal. Today 2001, 69 (1–4), 63–73.
- 33 Ethylene and its Industrial Derivatives (Ed: S. A. Miller), Benn, London 1969, 546–548.
- 34 M. Bayat, M. Hamidi, Z. Dehghani, M. R. Rahimpour, J. Nat. Gas Sci. Eng. 2013, 12, 56–64.
- 35 R. Wolf, H. Gotze, Chem. Tech. 1962, 14 (10), 600–606.
- 36 H. Kanoh, T. Nishimura, A. Ayame, J. Catal. 1979, 57 (3), 372–379.
- 37 K. Lee, X. E. Verykios, R. Pitchai, Appl. Catal. 1988, 44 (1–2), 223–237.
- 38 K.-H. Jung, K.-H. Chung, M.-Y. Kim, J.-H. Kim, G. Seo, Korean J. Chem. Eng. 1999, 16 (3), 396–400.
- 39 R. P. Nielsen (Shell), DE-OS 2159346, 1971.
- 40 R. P. Nielsen, J. H. La Rochelle (Shell), US Patent 4012425, 1972.
- 41 A. M. Lauritzen (Shell), EP 0266015, 1987.
- 42 M. M. Bashin, G. W. Warner (UCC), EP 75938, 1982.
- 43 G. L. Montrasi, G. C. Battiston, Oxid. Commun. 1983, 3 (3–4), 259–267.
- 44 J. M. Berty, Chem. Eng. Commun. 1989, 82, 223–227.
- 45 P. D. Klugherz, P. Harriott, AIChE J. 1971, 17 (4), 856–866.
- 46 R. A. von Santen, H. P. C. E. Kuipers, Adv. Catal. 1987, 35, 265–321.
- 47 W. M. H. Sachtler, C. Backx, R. A. Van Santen, Catal. Rev.: Sci. Eng. 1981, 23 (1–2), 127–149.
- 48 L. Petrov, A. Eliyas, D. Shopov, Appl. Catal. 1986, 24 (1), 145–161.
- 49 A. Eliyas, L. Petrov, D. Shopov, Appl. Catal. 1988, 41 (1), 39–52.
- 50 L. Gonçalves Ribeiro, M. E. Santos Taqueda, Chem. Eng. Technol. 2015, 38 (12), 2235–2242.
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