Combustion behavior, mechanical performance and application for vinyl acetate–ethylene copolymer emulsion containing melamine amino trimethyl phosphate and sodium lignosulfonate
Jinhan Lu
China Academy of Building Research, Beijing, China
Contribution: Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Xuan Sun
China Academy of Building Research, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Supervision (lead), Writing - review & editing (supporting)
Search for more papers by this authorGaëlle Fontaine
Univ. Lille, CNRS, ENSCL, UMR 8207, UMET, Unité Matériaux et Transformations, Lille, France
Contribution: Writing - review & editing (lead)
Search for more papers by this authorSerge Bourbigot
Univ. Lille, CNRS, ENSCL, UMR 8207, UMET, Unité Matériaux et Transformations, Lille, France
Institut Universitaire de France (IUF), Paris, France
Contribution: Writing - review & editing (lead)
Search for more papers by this authorZhilin Chen
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, China
Contribution: Supervision (lead)
Search for more papers by this authorCorresponding Author
Maohai Wang
China Academy of Building Research, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Supervision (lead)
Search for more papers by this authorCorresponding Author
Peng Jiang
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Project administration (lead)
Search for more papers by this authorJinhan Lu
China Academy of Building Research, Beijing, China
Contribution: Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Xuan Sun
China Academy of Building Research, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Supervision (lead), Writing - review & editing (supporting)
Search for more papers by this authorGaëlle Fontaine
Univ. Lille, CNRS, ENSCL, UMR 8207, UMET, Unité Matériaux et Transformations, Lille, France
Contribution: Writing - review & editing (lead)
Search for more papers by this authorSerge Bourbigot
Univ. Lille, CNRS, ENSCL, UMR 8207, UMET, Unité Matériaux et Transformations, Lille, France
Institut Universitaire de France (IUF), Paris, France
Contribution: Writing - review & editing (lead)
Search for more papers by this authorZhilin Chen
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, China
Contribution: Supervision (lead)
Search for more papers by this authorCorresponding Author
Maohai Wang
China Academy of Building Research, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Supervision (lead)
Search for more papers by this authorCorresponding Author
Peng Jiang
Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing, China
Correspondence
Xuan Sun and Maohai Wang, China Academy of Building Research, Beisanhuan East Road, Chaoyang District, Beijing 100013, China.
Email: [email protected]; [email protected]
Peng Jiang, Research Institute of Wood Industry, Chinese Academy of Forestry, Xiangshan Road, Haidian District, Beijing 100091, China.
Email: [email protected]
Contribution: Project administration (lead)
Search for more papers by this authorAbstract
An intumescent-flame-retardant vinyl acetate–ethylene copolymer (IFR/VAE) compound has been prepared by blending with a complex of melamine amino trimethyl phosphate (M-AT) and sodium lignosulfonate (SL). Then, this obtained IFR/VAE polymer was applied as adhesives for producing the flame-retardant plywood. The IFR VAE sample (VAE/M-AT3/SL1) with a mass ratio 3:1 (M-AT to SL) showed an enhanced amount of char residue, limiting oxygen index (LOI) value and tensile strength value to 20.6 wt%, 32 vol% and 19.3 MPa, which have been increased by 796%, 600%, and 56% compared to that of neat VAE. The cone calorimeter result showed that the peak of heat release rate (pHRR) of VAE/M-AT3/SL1 sample was reduced by 48% compared to the control one. Additionally, the second peak of HRR of sample IFRPW/15 L/15 (containing 15 wt% M-AT3/SL1 in the plywood adhesive layer) presented a reduction of 29% compared to that of the sample PW/15 L (neat plywood). It is assigned to the formation of phospho-carbonaceous structure during combustion, thus the flame-retardancy of plywood has been greatly enhanced. Thus, this work provides an economical and applicable fire-retardant VAE adhesive formula for producing plywood materials with good performances.
CONFLICT OF INTEREST STATEMENT
The authors declare no competing financial interests.
Open Research
DATA AVAILABILITY STATEMENT
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| app54779-sup-0001-supinfo.docxWord 2007 document , 7 MB | Figure S1: DTG curves of intumescent flame-retardant VAE polymer containing different mass ratio of M-AT to SL under nitrogen atmosphere. Figure S2: (a) CO production (COP) and (b) smoke production rate (SPR) of the IFR VAE polymer during cone calorimetry test containing representative mass ratio of M-AT to SL. Figure S3: (a) CO production (COP) and (b) smoke production rate (SPR) of the flame-retardant plywood during cone calorimetry test containing representative mass ratio of M-AT to SL. |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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