RESEARCH ARTICLE

Synthesis of fluorine contained hyperbranched polysiloxane and their effect on the thermal conductivity of epoxy resins

Corresponding Author

Yuan Jia

[email protected]

orcid.org/0000-0002-2823-0524

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Correspondence

Yuan Jia, The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, Shaanxi 710065, People's Republic of China.

Email: [email protected]

Contribution: Data curation (lead)

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Juxiang Yang,

Juxiang Yang

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Methodology (lead)

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Zhen Liu,

Zhen Liu

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Conceptualization (equal)

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Beibei Li,

Beibei Li

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Investigation (equal)

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Yuan Jia,

Corresponding Author

Yuan Jia

[email protected]

orcid.org/0000-0002-2823-0524

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Correspondence

Yuan Jia, The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, Shaanxi 710065, People's Republic of China.

Email: [email protected]

Contribution: Data curation (lead)

Search for more papers by this author

Juxiang Yang,

Juxiang Yang

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Methodology (lead)

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Zhen Liu,

Zhen Liu

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Conceptualization (equal)

Search for more papers by this author

Beibei Li,

Beibei Li

The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, College of Chemical Engineering, Xi'an University, Xi'an, People's Republic of China

Contribution: Investigation (equal)

Search for more papers by this author

First published: 05 November 2022

https://doi.org/10.1002/app.53315

Funding information: Natural Science Foundation of Shaanxi Province, Grant/Award Number: 2021JM-509; Research Team of Xi'an University, Grant/Award Number: XAWLKYTD018; Science and Technology Program of Xi'an, Grant/Award Number: 21XJZZ0066; Scientific Research Program of Education Department of Shaanxi Province, Grant/Award Number: 21JK0870; Xi'an Association for Science and Technology Young Talent Promotion Project, Grant/Award Number: 095920211335; Youth Innovation Team of Shaanxi Universities

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Abstract

To improve the thermostability properties of epoxy (EP) resin, two kinds of novel hyperbranched polysiloxanes containing fluorine were prepared via the sol–gel process and the convenient transesterification process, respectively (F-HBPSi-1 and F-HBPSi-2). These two prepared F-HBPSi were then used as modifier phased to blend with EP to obtain two new series polymer alloys F-HBPSi-1/EP and F-HBPSi-2/EP. The dielectric properties and thermal conductivities of the cured F-HBPSi/EP resins were measured, while their thermal properties were also investigated by thermogravimetry (TG). The results showed that both the thermal conductivities and the thermostability properties of these two F-HBPSi/EP were increased effectively, without further damaging their dielectric properties. Meanwhile, the F-HBPSi-2/EP exhibits better thermal conductivities and thermostability properties than that of F-HBPSi-1/EP. The improved overall performance of F-HBPSi-2/EP can be attributed to the low viscosity and excellent compatibility of F-HBPSi-2, as well as the good synergism between fluorine and silicon.

CONFLICT OF INTEREST

The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results.

Open Research

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Volume140, Issue3

January 15, 2023

e53315

Synthesis of fluorine contained hyperbranched polysiloxane and their effect on the thermal conductivity of epoxy resins

Abstract

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

REFERENCES

References

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Synthesis of fluorine contained hyperbranched polysiloxane and their effect on the thermal conductivity of epoxy resins

Abstract

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

REFERENCES

References

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