Volume 139, Issue 16 51996
ARTICLE

Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study

Zoran M. Marković

Zoran M. Marković

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

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Danica Z. Zmejkoski

Danica Z. Zmejkoski

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

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Milica D. Budimir

Milica D. Budimir

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

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Nikol Bugárová

Nikol Bugárová

Slovak Academy of Sciences, Polymer Institute, Bratislava, Slovakia

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Angela Kleinová

Angela Kleinová

Slovak Academy of Sciences, Polymer Institute, Bratislava, Slovakia

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Sanja B. Kuzman

Sanja B. Kuzman

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

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Zdeno Špitalský

Zdeno Špitalský

Slovak Academy of Sciences, Polymer Institute, Bratislava, Slovakia

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Vladimir B. Pavlović

Vladimir B. Pavlović

Faculty of Agriculture, University of Belgrade, Zemun, Serbia

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Dušan D. Milivojević

Dušan D. Milivojević

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

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Biljana M. Todorović Marković

Corresponding Author

Biljana M. Todorović Marković

Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia

Correspondence

Biljana M. Todorović Marković, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, P.O.B. 522, 11001 Belgrade, Serbia

Email: [email protected]

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First published: 02 December 2021
Citations: 2

Funding information: Agentúra Ministerstva Školstva, Vedy, Výskumu a Športu SR, Grant/Award Number: 2/0051/20; European Cooperation in Science and Technology, Grant/Award Number: CA16217; Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja, Grant/Award Number: 451-03-2/2021-14/20-0302102

Abstract

Due to their unique structural properties bacterial cellulose (BC) hydrogels find possible usage in many fields such as cosmetology, food industry, or medicine. In this study, photoactive BC hydrogels are investigated through modifications of their structural, mechanical, and pro-oxidant properties resulting from graphene quantum dots (GQDs) encapsulation. Detailed structural analysis is conducted by atomic force microscopy, transmission electron microscopy and scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction method. Dynamic mechanical analysis is performed to study the changes in storage modulus, loss modulus and tan δ. Pro-oxidative properties of new designed composites are tested by electron paramagnetic resonance (EPR). Structural and mechanical analyses show successful encapsulation of GQDs into BC whereas EPR measurements indicate high potential of these composites for singlet oxygen production.

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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