Synthesis of carbon quantum dots to fabricate ultraviolet-shielding poly(vinylidene fluoride) films
Li Dong
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Search for more papers by this authorZhengrong Xiong
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Search for more papers by this authorXiangdong Liu
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Search for more papers by this authorCorresponding Author
Dekun Sheng
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Correspondence to: D. Sheng ([email protected]) and Y. Yang ([email protected])Search for more papers by this authorYan Zhou
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Search for more papers by this authorCorresponding Author
Yuming Yang
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Correspondence to: D. Sheng ([email protected]) and Y. Yang ([email protected])Search for more papers by this authorLi Dong
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Search for more papers by this authorZhengrong Xiong
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Search for more papers by this authorXiangdong Liu
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Search for more papers by this authorCorresponding Author
Dekun Sheng
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
Correspondence to: D. Sheng ([email protected]) and Y. Yang ([email protected])Search for more papers by this authorYan Zhou
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Search for more papers by this authorCorresponding Author
Yuming Yang
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
University of Science and Technology of China, Hefei 230026, China
Correspondence to: D. Sheng ([email protected]) and Y. Yang ([email protected])Search for more papers by this authorABSTRACT
The paper presents a simple and effective approach to fabricating a poly(vinylidene fluoride) (PVDF) film with excellent ultraviolet (UV) shielding performance. Carbon quantum dots (CQDs) with a highly UV absorbing property were made via a hydrothermal reaction and were then added to a poly(vinyl alcohol) (PVA) solution. The PVDF membrane pretreated with an alkaline solution was immersed in the prepared CQD/PVA solution to coat a UV-shielding layer on the film surface. Fourier transform infrared spectroscopy, X-ray photoelectron spectrometry, X-ray diffraction, transmission electron microscopy, and UV–visible spectrophotometry were applied to study the structure, morphology, and optical performance of the CQD particles. The stability and UV-shielding performance of the obtained PVDF-OH@CQDs/PVA composite film were further investigated. The results showed that the CQD particles with diameter of 18 nm could be well dispersed in solution. Additionally, the CQDs had fairly high UV absorbance, and the PVDF-OH@CQDs/PVA composite film could shield the UV light completely. The method described in this paper is a promising one for fabricating UV-shielding composite films. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47555.
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