RESEARCH ARTICLE

Bio-derived nanosilica-anchored Cu(II)-organoselenium complex as an efficient retrievable catalyst for alcohol oxidation

Rajjyoti Gogoi

orcid.org/0000-0002-5555-6693

Department of Chemistry, Dibrugarh University, Dibrugarh, India

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (equal), Investigation (equal), Methodology (equal), Resources (equal), Software (equal), Visualization (equal)

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Geetika Borah,

Corresponding Author

Geetika Borah

[email protected]

orcid.org/0000-0002-5781-1694

Department of Chemistry, Dibrugarh University, Dibrugarh, India

Correspondence

Geetika Borah, Department of Chemistry, Dibrugarh University, Dibrugarh, India.

Email: [email protected]

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (equal), Investigation (equal), Resources (equal), Supervision (equal)

Search for more papers by this author

Rajjyoti Gogoi,

Rajjyoti Gogoi

orcid.org/0000-0002-5555-6693

Department of Chemistry, Dibrugarh University, Dibrugarh, India

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (equal), Investigation (equal), Methodology (equal), Resources (equal), Software (equal), Visualization (equal)

Search for more papers by this author

Geetika Borah,

Corresponding Author

Geetika Borah

[email protected]

orcid.org/0000-0002-5781-1694

Department of Chemistry, Dibrugarh University, Dibrugarh, India

Correspondence

Geetika Borah, Department of Chemistry, Dibrugarh University, Dibrugarh, India.

Email: [email protected]

Contribution: Conceptualization (equal), Data curation (equal), Formal analysis (equal), Investigation (equal), Resources (equal), Supervision (equal)

Search for more papers by this author

First published: 09 September 2021

https://doi.org/10.1002/aoc.6416

Citations: 1

Funding information: UGC, New Delhi, India

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Abstract

A new copper(II) complex supported onto rice-husk-derived nanosilica was prepared from 2,6-bis((phenylselanyl)methyl)pyridine, salicylaldehyde and copper acetate monohydrate, Cu(OAc)₂·H₂O. The as-synthesized complex Cu(II)SeNSe@imine-nanoSiO₂ (Complex I) was extensively characterized with FT-IR, powder XRD, SEM-EDX, solid-state UV-Vis, ESR, XPS, TGA and BET surface area analysis. The catalytic activity of the complex was explored for alcohol oxidation reactions using H₂O₂ as oxidant and acetonitrile as solvent. For comparison, we have also prepared an analogous homogeneous catalyst (Complex II) and characterized it with FT-IR, UV-Vis, LC-MS and ESR analyses. Its catalytic activity was also screened to the same reaction. The immobilized catalyst showed better efficiency with 75%–95% isolated yield compared with the homogeneous one for alcohol oxidation with at least five times recyclability without profound loss in activity.

Highlights

This is the first report of immobilized copper complex with Se–N–Se pincer ligand. Moreover, we have used bio-derived nanosilica as a solid support.
The alcohols are oxidized under environmentally benign mild reaction conditions using hydrogen peroxide as an oxidant.
The catalytic performance of the supported complex was compared with an analogous unsupported complex.

CONFLICT OF INTEREST

The authors declare that there is no conflict of interest regarding the publication of this article.

Open Research

DATA AVAILABILITY STATEMENT

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Supporting Information

Filename

Description

aoc6416-sup-0001-Supplementary_Information_file_(clean).docxWord 2007 document , 2.5 MB

Figure S1. FT-IR spectrum of ligand (L₁)

Figure S2. HRMS spectrum of ligand (L₁)

Figure S3. LCMS of the complex II

Figure S4. FT-IR spectrum of Cu (II)-Se-N-Se-imine (complex II)

Figure S5. XPS Survey scan of Cu (II)SeNSe@imine-nanoSiO₂

Figure S6. TGA and DTG curve of APTES@nanoSiO₂

Figure S7. TGA and DTG curve of imine@nanoSiO₂

Figure S8. TGA and DTG curve of Cu (II)SeNSe@imine-nanoSiO₂

Figure S9. Solid state UV–vis spectra of (a) imine@nanoSiO₂ (b)2,6-bis((phenylselanyl)methyl) pyridine ligand, (c) Cu (II)SeNSe@imine-nanoSiO₂

Figure S10. UV–vis spectrum of complex II

Figure S11. Hot Filtration Test

Figure S12. Reusability of the catalyst (complex I)

Figure S13. SEM image of the catalyst after 5th cycle

Figure S14. EDX spectrum of catalyst after 5th cycle (complex I)

Figure S15. PXRD of reused catalyst, Cu (II)SeNSe@imine-nanoSiO₂

Figure S16. EPR spectrum of complex I after 1st cycle of reaction

Table S1. Optimization of reaction conditions for oxidation of 1-phenyl ethanol with complex II

Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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Volume35, Issue12

December 2021

e6416

Bio-derived nanosilica-anchored Cu(II)-organoselenium complex as an efficient retrievable catalyst for alcohol oxidation

Abstract

Highlights

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

Supporting Information

REFERENCES

Citing Literature

References

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Bio-derived nanosilica-anchored Cu(II)-organoselenium complex as an efficient retrievable catalyst for alcohol oxidation

Abstract

Highlights

CONFLICT OF INTEREST

Open Research

DATA AVAILABILITY STATEMENT

Supporting Information

REFERENCES

Citing Literature

References

Related

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