Inside Cover: Fe/Fe3C Boosts H2O2 Utilization for Methane Conversion Overwhelming O2 Generation (Angew. Chem. Int. Ed. 16/2021)
Graphical Abstract
Fe-Nx in the low-spin state is the active site in the homolytic cleavage of H2O2 to .OH, as reported by Wenting Wu, Mingbo Wu, and co-workers in their Research Article on page 8889. Fe/Fe3C promotes the formation of Fe-Nx sites for this homolytic cleavage process, enabling the highly selective oxidation of CH4 to HCOOH under light irradiation.