Angewandte Chemie International Edition
Volume 59, Issue 12 p. 4593
Cover Picture
Free Access

Cover Picture: Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance (Angew. Chem. Int. Ed. 12/2020)

Dr. Bin-Wen Liu, 

Dr. Bin-Wen Liu

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China

Search for more papers by this author
Xiao-Ming Jiang, 

Corresponding Author

Xiao-Ming Jiang

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China

Search for more papers by this author
Bing-Xuan Li, 

Bing-Xuan Li

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China

Search for more papers by this author
Hui-Yi Zeng, 

Hui-Yi Zeng

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China

Search for more papers by this author
Prof. Guo-Cong Guo, 

Corresponding Author

Prof. Guo-Cong Guo

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155#, Fuzhou, Fujian, 350002 P. R. China

Search for more papers by this author
First published: 26 February 2020
https://doi.org/10.1002/anie.202002283
Citations: 5

Graphical Abstract

A new salt-inclusion chalcogenide that features an unprecedented 3D [Ga3S6] framework with nanosized tunnels is presented by X.-M. Jiang, G.-C. Guo, and co-workers in their Communication on page 4856. The covalent host and ionic guests synergistically contribute to a large nonlinear optical (NLO) coefficient and ultrawide bandgap, which indicates potential for application in infrared NLO materials.

Description unavailable

image

A new salt-inclusion chalcogenide that features an unprecedented 3D [Ga3S6] framework with nanosized tunnels is presented by X.-M. Jiang, G.-C. Guo, and co-workers in their Communication on page 4856. The covalent host and ionic guests synergistically contribute to a large nonlinear optical (NLO) coefficient and ultrawide bandgap, which indicates potential for application in infrared NLO materials.

Cycloisomerization

The de novo synthesis of hydroxylated benzofuran and the realization of a collective total synthesis of hydroxylated benzofuran-containing natural products are described by S. Zhu et al. in their Research Article on page 4670.
image

Protein Delivery

In their Research Article on page 4711, Y. Cheng et al. report that dendrimers modified with a dipicolylamine/zinc(II) complex deliver cargo proteins and peptides into the cytosol while maintaining their bioactivity after intracellular release.
image

Supramolecular Chemistry

J. H. van Esch et al. describe in their Communication on page 4830 the preparation of biomimetic strain-stiffening supramolecular hydrogels through the self-assembly of molecular gelators.
image

    The full text of this article hosted at iucr.org is unavailable due to technical difficulties.