Proton Insertion Chemistry of a Zinc–Organic Battery
Zhiwei Tie
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorLuojia Liu
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorShenzhen Deng
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorProf. Dongbing Zhao
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhiqiang Niu
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorZhiwei Tie
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorLuojia Liu
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorShenzhen Deng
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorProf. Dongbing Zhao
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Zhiqiang Niu
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071 P. R. China
Search for more papers by this authorDedicated to 100th anniversary of Nankai University
Graphical Abstract
Proton insertion chemistry based on organic aqueous zinc-ion batteries (ZIBs) was developed in a mild electrolyte. The H+ insertion/extraction endows the battery system with enhanced electrochemical performance. Moreover, the proton insertion chemistry will broaden horizons of aqueous ZIBs.
Abstract
Proton storage in rechargeable aqueous zinc-ion batteries (ZIBs) is attracting extensive attention owing to the fast kinetics of H+ insertion/extraction. However, it has not been achieved in organic materials-based ZIBs with a mild electrolyte. Now, aqueous ZIBs based on diquinoxalino [2,3-a:2′,3′-c] phenazine (HATN) in a mild electrolyte are developed. Electrochemical and structural analysis confirm for the first time that such Zn–HATN batteries experience a H+ uptake/removal behavior with highly reversible structural evolution of HATN. The H+ uptake/removal endows the Zn–HATN batteries with enhanced electrochemical performance. Proton insertion chemistry will broaden the horizons of aqueous Zn–organic batteries and open up new opportunities to construct high-performance ZIBs.
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