A Hollow Multi-Shelled Structure for Charge Transport and Active Sites in Lithium-Ion Capacitors
Ruyi Bi
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Nan Xu
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorHao Ren
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorProf. Nailiang Yang
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorDr. Yonggang Sun
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Anmin Cao
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Ranbo Yu
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
Laboratory of Material Processing and Mold, Ministry of Education, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dan Wang
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorRuyi Bi
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDr. Nan Xu
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorHao Ren
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorProf. Nailiang Yang
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorDr. Yonggang Sun
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Anmin Cao
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology and CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Ranbo Yu
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, No. 30, Xueyuan Road, Haidian District, Beijing, 100083 P. R. China
Laboratory of Material Processing and Mold, Ministry of Education, Zhengzhou University, Zhengzhou, 450001 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Dan Wang
State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, 1 North 2nd Street, Zhongguancun, Haidian District, Beijing, 100190 P. R. China
University of Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorGraphical Abstract
Live LICs: The balance of active sites and charge transport allow Nb2O5 with a hollow multi-shelled structure to deliver excellent energy density, an ultrahigh power density, and good cycle stability for high-performance Li-ion capacitors (LICs).
Abstract
The lithium-ion capacitor (LIC) has attracted tremendous research interest because it meets both the requirement on high energy and power densities. The balance between effective surface areas and mass transport is highly desired to fabricate the optimized electrode material for LIC. Now, triple-shelled (3S) Nb2O5 hollow multi-shelled structures (HoMSs) were synthesized for the first time through the sequential templating approach and then applied for the anode of LIC. The unique structure of HoMSs, such as large efficient surface area, hierarchical pores, and multiple shells, provides abundant reaction sites, decreases the electron transport resistance, and increases the diffusion rate for ion transport. In this case, the best combination performance has been achieved among all the reported Nb2O5-based materials, which delivered an excellent energy and power densities simultaneously, and superb cycling stability.
Supporting Information
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