Switching in Metal–Organic Frameworks
Dr. Fahime Bigdeli
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
These authors contributed equally to this work.
Search for more papers by this authorChristina T. Lollar
Department of Chemistry, Texas A&M University, College Station, TX, 77843 USA
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Prof. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorCorresponding Author
Prof. Dr. Hong-Cai Zhou
Department of Chemistry, Texas A&M University, College Station, TX, 77843 USA
Department of Materials Science and Engineering, Texas A&M University, College Station, TX, 77843 USA
Search for more papers by this authorDr. Fahime Bigdeli
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
These authors contributed equally to this work.
Search for more papers by this authorChristina T. Lollar
Department of Chemistry, Texas A&M University, College Station, TX, 77843 USA
These authors contributed equally to this work.
Search for more papers by this authorCorresponding Author
Prof. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorCorresponding Author
Prof. Dr. Hong-Cai Zhou
Department of Chemistry, Texas A&M University, College Station, TX, 77843 USA
Department of Materials Science and Engineering, Texas A&M University, College Station, TX, 77843 USA
Search for more papers by this authorGraphical Abstract
A switch in time: Although dynamic and flexible metal–organic frameworks (MOFs) have been closely assessed in recent literature, analysis into the subcategory of switchable MOFs has been comparably lacking. By virtue of their steady rise in popularity, MOFs with intriguing, switchable responses to light, temperature, pressure, redox species and guests are surveyed.
Abstract
In recent years, metal–organic frameworks (MOFs) have become an area of intense research interest because of their adjustable pores and nearly limitless structural diversity deriving from the design of different organic linkers and metal structural building units (SBUs). Among the recent great challenges for scientists include switchable MOFs and their corresponding applications. Switchable MOFs are a type of smart material that undergo distinct, reversible, chemical changes in their structure upon exposure to external stimuli, yielding interesting technological applicability. Although the process of switching shares similarities with flexibility, very limited studies have been devoted specifically to switching, while a fairly large amount of research and a number of Reviews have covered flexibility in MOFs. This Review focuses on the properties and general design of switchable MOFs. The switching activity has been delineated based on the cause of the switching: light, spin crossover (SCO), redox, temperature, and wettability.
Conflict of interest
The authors declare no conflict of interest.
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