Smart Transformation of a Polyhedral Oligomeric Silsesquioxane Shell Controlled by Thiolate Silver(I) Nanocluster Core in Cluster@Clusters Dendrimers
Si Li
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
These authors contributed equally to this work.
Search for more papers by this authorZhao-Yang Wang
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Guang-Gang Gao
School of Materials Science and Engineering, University of Jinan, Jinan, 250022 China
Search for more papers by this authorBing Li
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorPeng Luo
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorYu-Jin Kong
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorProf. Dr. Hong Liu
School of Materials Science and Engineering, University of Jinan, Jinan, 250022 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Shuang-Quan Zang
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorSi Li
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
These authors contributed equally to this work.
Search for more papers by this authorZhao-Yang Wang
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
These authors contributed equally to this work.
Search for more papers by this authorProf. Dr. Guang-Gang Gao
School of Materials Science and Engineering, University of Jinan, Jinan, 250022 China
Search for more papers by this authorBing Li
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorPeng Luo
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorYu-Jin Kong
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorProf. Dr. Hong Liu
School of Materials Science and Engineering, University of Jinan, Jinan, 250022 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Shuang-Quan Zang
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001 China
Search for more papers by this authorGraphical Abstract
An atom-precise Ag12@POSS6 dendritic complex (POSS=polyhedral oligomeric silsesquioxane) has been synthesized. The central silver(I) cluster core underwent a reversible structural transformation with solvent stimuli, leading to the rearrangement of the shell POSS clusters from pseudo-octahedral to quasi-octahedral.
Abstract
Using polyhedral oligomeric silsesquioxane (POSS) modified by a thiol group as a protected ligand, atom-precise multi-heteorocluster-based dendrimers Ag12@POSS6 (1 a and 1 b) were assembled. Through the reactive −SH groups, six POSS shell ligands stabilize the central 12-core silver(I) cluster by diverse Ag−S interactions. When such Ag12@POSS6 complex was stimulated by different solvents (acetone or tetrahydrofuran), the core Ag12 silver(I) cluster underwent reversible structural transformation between flattened cubo-octahedral (in 1 a) and normal cubo-octahedral (in 1 b); concomitantly shell POSS clusters rearranged from pseudo-octahedral to quasi-octahedral. Furthermore, the film matrix modified by 1 a or 1 b showed different hydrophobicity.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| anie201807548-sup-0001-misc_information.pdf878 KB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1
- 1aI. Chakraborty, T. Pradeep, Chem. Rev. 2017, 117, 8208–8271;
- 1bR.-C. Jin, C.-J. Zeng, M. Zhou, Y.-X. Chen, Chem. Rev. 2016, 116, 10346–10413;
- 1cH. Schmidbaur, A. Schier, Angew. Chem. Int. Ed. 2015, 54, 746–784; Angew. Chem. 2015, 127, 756–797;
- 1dV. W.-W. Yam, V. K.-M. Au, S. Y.-L. Leung, Chem. Rev. 2015, 115, 7589–7728;
- 1eC. P. Joshi, M. S. Bootharaju, O. M. Bakr, J. Phys. Chem. Lett. 2015, 6, 3023–3035;
- 1fQ.-M. Wang, Y.-M. Lin, K.-G. Liu, Acc. Chem. Res. 2015, 48, 1570–1579;
- 1gO. Fuhr, S. Dehnen, D. Fenske, Chem. Soc. Rev. 2013, 42, 1871–1906;
- 1hH. Schmidbaur, A. Schier, Chem. Soc. Rev. 2012, 41, 370–412.
- 2
- 2aZ.-Y. Wang, M.-Q. Wang, Y.-L. Li, P. Luo, T.-T. Jia, R.-W. Huang, S.-Q. Zang, T. C. W. Mak, J. Am. Chem. Soc. 2018, 140, 1069–1076;
- 2bR.-W. Huang, Y.-S. Wei, X.-Y. Dong, X.-H. Wu, C.-X. Du, S.-Q. Zang, T. C.-W. Mak, Nat. Chem. 2017, 9, 689–697;
- 2cW.-T. Chang, P.-Y. Lee, J.-H. Liao, K. K. Chakrahari, S. Kahlal, Y.-C. Liu, M.-H. Chiang, J.-Y. Saillard, C. W. Liu, Angew. Chem. Int. Ed. 2017, 56, 10178–10182; Angew. Chem. 2017, 129, 10312–10316;
- 2dS. Jin, S.-X. Wang, Y.-B. Song, M. Zhou, J. Zhong, J. Zhang, A.-D. Xia, Y. Pei, M. Chen, P. Li, M.-Z. Zhu, J. Am. Chem. Soc. 2014, 136, 15559–15565;
- 2eS.-X. Wang, X.-M. Meng, A. Das, T. Li, Y.-B. Song, T.-T. Cao, X.-Y. Zhu, M.-Z. Zhu, R.-C. Jin, Angew. Chem. Int. Ed. 2014, 53, 2376–2380; Angew. Chem. 2014, 126, 2408–2412;
- 2fX. Yuan, Q. Yao, Y. Yu, Z. Luo, X. Dou, J.-P. Xie, J. Phys. Chem. Lett. 2013, 4, 1811–1815;
- 2gM. Pelton, Y. Tang, O. M. Bakr, F. Stellacci, J. Am. Chem. Soc. 2012, 134, 11856–11859;
- 2hG. Li, Z. Lei, Q.-M. Wang, J. Am. Chem. Soc. 2010, 132, 17678–17679.
- 3
- 3aS. Jin, S.-X. Wang, L. Xiong, M. Zhou, S. Chen, W.-J. Du, A.-D. Xia, Y. Pei, M.-Z. Zhu, Chem. Mater. 2016, 28, 7905–7911;
- 3bK. Zheng, M. I. Setyawati, T. Lim, D. T. Leong, J.-P. Xie, ACS Nano 2016, 10, 7934–7942;
- 3cY. Tao, M. Li, J. Ren, X. Qu, Chem. Soc. Rev. 2015, 44, 8636–8663;
- 3dC. P. Joshi, M. S. Bootharaju, M. J. Alhilaly, O. M. Bakr, J. Am. Chem. Soc. 2015, 137, 11578–11581;
- 3eA. Desireddy, B. E. Conn, J. Guo, B. Yoon, R. N. Barnett, B. M. Monahan, K. Kirschbaum, W. P. Griffith, R. L. Whetten, U. Landman, T. P. Bigioni, Nature 2013, 501, 399–402;
- 3fX. Yuan, Z. Luo, Y. Yu, Q. Yao, J.-P. Xie, Chem. Asian J. 2013, 8, 858–871;
- 3gY.-Z. Lu, W. Chen, Chem. Soc. Rev. 2012, 41, 3594–3623.
- 4
- 4aH.-Y. Yang, J.-Z. Yan, Y. Wang, G.-C. Deng, H.-F. Su, X.-J. Zhao, C.-F. Xu, B.-K. Teo, N.-F. Zheng, J. Am. Chem. Soc. 2017, 139, 16113–16116;
- 4bZ. Wang, H.-F. Su, Y.-Z. Tan, S. Scheinc, S.-C. Lin, W. Liue, S.-A. Wang, W.-G. Wang, C.-H. Tung, D. Sun, L.-S. Zheng, Proc. Natl. Acad. Sci. USA 2017, 114, 12132–12137;
- 4cA. M. Polgar, F. Weigend, A. Zhang, M. J. Stillman, J. F. Corrigan, J. Am. Chem. Soc. 2017, 139, 14045–14048;
- 4dS. Yang, J. Chai, Y. Song, J. Fan, T. Chen, S. Wang, H. Yu, X. Li, M.-Z. Zhu, J. Am. Chem. Soc. 2017, 139, 5668–5671;
- 4eM. Qu, H. Li, L.-H. Xie, S.-T. Yan, J.-R. Li, J.-H. Wang, C.-Y. Wei, Y.-W. Wu, X.-M. Zhang, J. Am. Chem. Soc. 2017, 139, 12346–12349;
- 4fS. Bestgen, O. Fuhr, B. Breitung, V. S. Kiran, Chakravadhanula, G. Guthausen, F. Hennrich, W. Yu, M. M. Kappes, P. W. Roeskya, D. Fenske, Chem. Sci. 2017, 8, 2235–2240;
- 4gM. Hailmann, N. Wolf, R. Renner, T. C. Schäfer, B. Hupp, A. Steffen, M. Finze, Angew. Chem. Int. Ed. 2016, 55, 10507–10511; Angew. Chem. 2016, 128, 10663–10667;
- 4hH.-Y. Yang, Y. Wang, H.-Q. Huang, L. Gell, L. Lehtovaara, S. Malola, H. Häkkinen, N.-F. Zheng, Nat. Commun. 2013, 4, 2422.
- 5
- 5aZ. Wang, H.-F. Su, M. Kurmoo, C.-H. Tung, D. Sun, L.-S. Zheng, Nat. Commun. 2018, 9, 2094;
- 5bJ.-W. Liu, L. Feng, H. Su, Z. Wang, Q.-Q. Zhao, X. Wang, C.-H. Tung, D. Sun, L.-S. Zheng, J. Am. Chem. Soc. 2018, 140, 1600–1603;
- 5cS. Li, X.-S. Du, B. Li, J.-Y. Wang, G.-P. Li, G.-G. Gao, S.-Q. Zang, J. Am. Chem. Soc. 2018, 140, 594–597;
- 5dH. Yang, J. Yan, Y. Wang, H. Su, L. Gell, X. Zhao, C. Xu, B. K. Teo, H. Häkkinen, N.-F. Zheng, J. Am. Chem. Soc. 2017, 139, 31–34;
- 5eM. S. Bootharaju, C. P. Joshi, M. J. Alhilaly, O. M. Bakr, Chem. Mater. 2016, 28, 3292–3297;
- 5fZ.-J. Guan, J.-L. Zeng, Z.-A. Nan, X.-K. Wan, Y.-M. Lin, Q.-M. Wang, Sci. Adv. 2016, 2, e 1600323;
- 5gY. Liu, B. K. Najafabadi, M. A. Fard, J. F. Corrigan, Angew. Chem. Int. Ed. 2015, 54, 4832–4835; Angew. Chem. 2015, 127, 4914–4917;
- 5hL. G. AbdulHalim, M. S. Bootharaju, Q. Tang, S. D. Gobbo, R. G. AbdulHalim, M. Eddaoudi, D.-E. Jiang, O. M. Bakr, J. Am. Chem. Soc. 2015, 137, 11970–11975;
- 5iF. Gruber, M. Jansen, Angew. Chem. Int. Ed. 2010, 49, 4924–4926; Angew. Chem. 2010, 122, 5044–5046;
- 5jD. Rais, J. Yau, D. M.-P. Mingos, R. Vilar, A. J.-P. White, D. J. Williams, Angew. Chem. Int. Ed. 2001, 40, 3464–3467;
10.1002/1521-3773(20010917)40:18<3464::AID-ANIE3464>3.0.CO;2-M CAS PubMed Web of Science® Google ScholarAngew. Chem. 2001, 113, 3572–3575.
- 6H. Liu, C.-Y. Song, R.-W. Huang, Y. Zhang, H. Xu, M.-J. Li, S.-Q. Zang, G.-G. Gao, Angew. Chem. Int. Ed. 2016, 55, 3699–3703; Angew. Chem. 2016, 128, 3763–3767.
- 7D. B. Cordes, P. D. Lickiss, F. Rataboul, Chem. Rev. 2010, 110, 2081–2173.
- 8Z. Li, B.-H. Tan, G. Jin, K. Li, C. He, Polym. Chem. 2014, 5, 6740–6753.
- 9
- 9aX.-S. Hou, G.-L. Zhu, L.-J. Ren, Z.-H. Huang, R.-B. Zhang, G. Ungar, L.-T. Yan, W. Wang, J. Am. Chem. Soc. 2018, 140, 1805–1811;
- 9bC. Ma, H. Wu, Z.-H. Huang, R.-H. Guo, M.-B. Hu, C. Kübel, L.-T. Yan, W. Wang, Angew. Chem. Int. Ed. 2015, 54, 15699–15704; Angew. Chem. 2015, 127, 15925–15930.
- 10
- 10aX.-H. Dong, B. Ni, M. Huang, C.-H. Hsu, R. Bai, W.-B. Zhang, A.-C. Shi, S. Z.-D. Cheng, Angew. Chem. Int. Ed. 2016, 55, 2459–2463; Angew. Chem. 2016, 128, 2505–2509;
- 10bW.-H. Hu, K.-W. Huang, C.-W. Chiou, S.-W. Kuo, Macromolecules 2012, 45, 9020–9028;
- 10cY. Li, W.-B. Zhang, I. Hsieh, G. Zhang, Y. Cao, X. Li, C. Wesdemiotis, B. Lotz, H. Xiong, S. Z.-D. Cheng, J. Am. Chem. Soc. 2011, 133, 10712–10715.
- 11
- 11aN. Sato, Y. Kuroda, T. Abe, H. Wada, A. Shimojima, K. Kuroda, Chem. Commun. 2015, 51, 11034–11037;
- 11bY.-C. Wu, S.-W. Kuo, J. Mater. Chem. 2012, 22, 2982–2991;
- 11cA. Boullanger, G. Gracy, N. Bibent, S. Devautour-Vinot, S. Clément, A. Mehdi, Eur. J. Inorg. Chem. 2012, 143–150;
- 11dK.-Y. Pu, Z. Luo, K. Li, J.-P. Xie, B. Liu, J. Phys. Chem. C 2011, 115, 13069–13075.
- 12
- 12aH.-L. Au-Yeung, A. Y.-Y. Tam, S. Y.-L. Leung, V. W.-W. Yam, Chem. Sci. 2017, 8, 2267–2276;
- 12bA. Raghuvanshi, C. Strohmann, J.-B. Tissot, S. Clément, A. Mehdi, S. Richeter, L. Viau, M. Knorr, Chem. Eur. J. 2017, 23, 16479–16483;
- 12cC.-H. Lu, F.-C. Chang, ACS Catal. 2011, 1, 481–488.
- 13
- 13aY. Wang, A. Vaneski, H. Yang, S. Gupta, F. Hetsch, S. V. Kershaw, W. Y. Teoh, H. Li, A. L. Rogach, J. Phys. Chem. C 2013, 117, 1857–1862;
- 13bD. Imai, Y. Satake, K. Noura, T. Nakahodo, H. Fujihara, Phosphorus Sulfur Silicon Relat. Elem. 2010, 185, 1206–1213;
- 13cC.-H. Lu, S.-W. Kuo, C.-F. Huang, F.-C. Chang, J. Phys. Chem. C 2009, 113, 3517–3524.
- 14
- 14aC.-B. Yu, L.-J. Ren, W. Wang, Macromolecules 2017, 50, 3273–3284;
- 14bM. Hailmann, N. Wolf, R. Renner, B. Hupp, A. Steffen, M. Finze, Chem. Eur. J. 2017, 23, 11684–11693;
- 14cN. Wolf, M. Hailmann, M. Finze, Eur. J. Inorg. Chem. 2017, 4459–4466;
- 14dJ. Ferrando-Soria, A. Fernandez, E. M. Pineda, S. A. Varey, R. W. Adams, I. J. Vitorica-Yrezabal, F. Tuna, G. A. Timco, C. A. Muryn, R. E.-P. Winpenny, J. Am. Chem. Soc. 2015, 137, 7644–7647;
- 14eH. D. Selby, B. K. Roland, Z.-P. Zheng, Acc. Chem. Res. 2003, 36, 933–944;
- 14fB. K. Roland, C. Carter, Z.-P. Zheng, J. Am. Chem. Soc. 2002, 124, 6234–6235.
- 15CCDC 1823273 (1 a) and 1823274 (1 b) contain the supplementary crystallographic data for this paper. These data are provided free of charge by The Cambridge Crystallographic Data Centre.
