Communication

Synthesis of Enantiopure Carbonaceous Nanotubes with Optical Activity^†

Shaohua Liu

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Yingying Duan,

Yingying Duan

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Xuejiao Feng,

Xuejiao Feng

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Prof. Jun Yang,

Prof. Jun Yang

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Prof. Shunai Che,

Corresponding Author

Prof. Shunai Che

[email protected]

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn Search for more papers by this author

Shaohua Liu,

Shaohua Liu

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Yingying Duan,

Yingying Duan

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

Search for more papers by this author

Xuejiao Feng,

Xuejiao Feng

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

Search for more papers by this author

Prof. Jun Yang,

Prof. Jun Yang

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

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Prof. Shunai Che,

Corresponding Author

Prof. Shunai Che

[email protected]

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240 (P.R. China) http://che.sjtu.edu.cn

First published: 28 May 2013

https://doi.org/10.1002/anie.201301199

Citations: 80

^†

This work was supported by the 973 project (2009CB930403) of China and Evonik Industry.

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Graphical Abstract

In one step, self-assembled helical polypyrrole nanotubes were carbonized to enantiopure chiral carbonaceous nanotubes with a partially graphitized nanostructure (see picture). The ordered helical arrangement of the carbon nanostructure resulted in enantiomeric materials with distinct optical activity. Moreover, their unique structure endowed them with high reversible storage capacity of lithium ions.

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Volume52, Issue27

July 1, 2013

Pages 6858-6862

Synthesis of Enantiopure Carbonaceous Nanotubes with Optical Activity^†

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Synthesis of Enantiopure Carbonaceous Nanotubes with Optical Activity^†