Activation Energy for the Self-Metalation Reaction of 2H-Tetraphenylporphyrin on Cu(111)†
Stefanie Ditze
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorMichael Stark
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorMartin Drost
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorDr. Florian Buchner
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorProf. Dr. Hans-Peter Steinrück
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorCorresponding Author
Dr. Hubertus Marbach
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)Search for more papers by this authorStefanie Ditze
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorMichael Stark
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorMartin Drost
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorDr. Florian Buchner
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorProf. Dr. Hans-Peter Steinrück
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Search for more papers by this authorCorresponding Author
Dr. Hubertus Marbach
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)
Lehrstuhl für Physikalische Chemie II and Interdisciplinary Center for Molecular Materials, Universität Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen (Germany)Search for more papers by this authorWe thank the German Science Foundation (DFG) for financial support through SFB 583 and the Excellence Cluster “Engineering of Advanced Materials” granted to the University of Erlangen-Nürnberg. We also thank Dr. Ole Lytken, Dr. Jie Xiao, Michael Röckert, and Dr. Wolfgang Hieringer for fruitful discussions and valuable input.
Graphical Abstract
By simply counting individual molecules in STM images after defined heating steps, the kinetic parameters and the activation energy of a complex surface reaction can be determined quantitatively. This procedure was demonstrated for the metalation of 2H-tetraphenylporphyrin (2HTPP) with substrate atoms on a Cu(111) surface.
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