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Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C₆F₅)₃-Stabilized Benzene–Ammonia and Benzene–Water Complexes^†

Corresponding Author

Prof. Xinping Wang

[email protected]

State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Xinping Wang, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Philip P. Power, Department of Chemistry, University of California, Davis, CA 95616 (USA)

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Prof. Philip P. Power,

Corresponding Author

Prof. Philip P. Power

[email protected]

Department of Chemistry, University of California, Davis, CA 95616 (USA)

Xinping Wang, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Philip P. Power, Department of Chemistry, University of California, Davis, CA 95616 (USA)

Search for more papers by this author

Prof. Xinping Wang,

Corresponding Author

Prof. Xinping Wang

[email protected]

State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Xinping Wang, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Philip P. Power, Department of Chemistry, University of California, Davis, CA 95616 (USA)

Search for more papers by this author

Prof. Philip P. Power,

Corresponding Author

Prof. Philip P. Power

[email protected]

Department of Chemistry, University of California, Davis, CA 95616 (USA)

Xinping Wang, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 (China)

Philip P. Power, Department of Chemistry, University of California, Davis, CA 95616 (USA)

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First published: 22 September 2011

https://doi.org/10.1002/anie.201103904

Citations: 35

^†

The authors thank the US National Science Foundation (CHE-0948417), the National Natural Science Foundation of China (21021062), and the Fundamental Research Funds for the Central Universities of China (020514330006) for financial support, and Albemarle Corporation for donation of B(C₆F₅)₃.

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Graphical Abstract

O/NH⋅⋅⋅π hydrogen bonds: Water–benzene and ammonia–benzene complexes are stabilized by the Lewis acid B(C₆F₅)₃ and provide rare structural (X-ray) and infrared spectroscopic data for water–benzene and ammonia–benzene complexes in the solid state (see picture). The infrared spectra of the complexes showed that the OH and NH stretching frequencies decrease significantly on benzene complexation.

Supporting Information

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Volume50, Issue46

November 11, 2011

Pages 10965-10968

Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C₆F₅)₃-Stabilized Benzene–Ammonia and Benzene–Water Complexes^†

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Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C6F5)3-Stabilized Benzene–Ammonia and Benzene–Water Complexes†

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Structural Characterization, Infrared Spectroscopy, and Theoretical Calculations for B(C₆F₅)₃-Stabilized Benzene–Ammonia and Benzene–Water Complexes^†