Gas-Phase Oxidation of Propane and 1-Butene with [V3O7]+: Experiment and Theory in Concert†
Sandra Feyel Dipl.-Chem.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorDetlef Schröder Dr.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorXavier Rozanska Dr.
Institut für Chemie, Humboldt Universität zu Berlin, Unter den Linden 6, 10099 Berlin, Germany, Fax: (+49) 30-2093-7136
Search for more papers by this authorJoachim Sauer Prof. Dr.
Institut für Chemie, Humboldt Universität zu Berlin, Unter den Linden 6, 10099 Berlin, Germany, Fax: (+49) 30-2093-7136
Search for more papers by this authorHelmut Schwarz Prof. Dr. Drs. h.c.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorSandra Feyel Dipl.-Chem.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorDetlef Schröder Dr.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorXavier Rozanska Dr.
Institut für Chemie, Humboldt Universität zu Berlin, Unter den Linden 6, 10099 Berlin, Germany, Fax: (+49) 30-2093-7136
Search for more papers by this authorJoachim Sauer Prof. Dr.
Institut für Chemie, Humboldt Universität zu Berlin, Unter den Linden 6, 10099 Berlin, Germany, Fax: (+49) 30-2093-7136
Search for more papers by this authorHelmut Schwarz Prof. Dr. Drs. h.c.
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany, Fax: (+49) 30-314-21102
Search for more papers by this authorFinancial support by the Fonds der Chemischen Industrie and the Deutsche Forschungsgemeinschaft (SFB 546) is acknowledged. X.R. and S.F. were supported by an Alexander von Humboldt fellowship and a GRK 352 fellowship, respectively.
Graphical Abstract
A good beginning is half the battle. Combined experimental and theoretical studies concerning the dehydrogenation of hydrocarbons by [V3O7]+ underline the decisive role of the initial CH activation step. Propane is found to be unreactive, whereas 1-butene rapidly reacts with [V3O7]+ (see picture).
Supporting Information
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