Rhenium Trichloride Dioxide, ReO2Cl3†
Joanna Supeł Dipl.-Chem.
FB Bio/Chem/Pharm, Institut für Chemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin, Germany, Fax: (+49) 30-8385-3310
Search for more papers by this authorKonrad Seppelt Prof. Dr.
FB Bio/Chem/Pharm, Institut für Chemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin, Germany, Fax: (+49) 30-8385-3310
Search for more papers by this authorJoanna Supeł Dipl.-Chem.
FB Bio/Chem/Pharm, Institut für Chemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin, Germany, Fax: (+49) 30-8385-3310
Search for more papers by this authorKonrad Seppelt Prof. Dr.
FB Bio/Chem/Pharm, Institut für Chemie, Anorganische und Analytische Chemie, Freie Universität Berlin, Fabeckstrasse 34–36, 14195 Berlin, Germany, Fax: (+49) 30-8385-3310
Search for more papers by this authorWe thank the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie for financial support.
Graphical Abstract
Re-discovery: The only rhenium(VII)–chlorine compound known previously was ReO3Cl, and chloride oxides of composition AO2Cl3 (A=nonmetal or metal) were completely unknown. The synthesis of ReO2Cl3 has now been achieved. The compound exists as a chlorine-bridged dimer (see Figure; Re red, O blue, Cl green) in the solid state, and as a monomer in solution.
References
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