Arylamine-Substituted Hexa-peri-hexabenzocoronenes: Facile Synthesis and Their Potential Applications as “Coaxial” Hole-Transport Materials†
Jishan Wu Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorMartin Baumgarten Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorMichael G. Debije Dr.
IRI, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands
Search for more papers by this authorJohn M. Warman Prof. Dr.
IRI, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands
Search for more papers by this authorKlaus Müllen Prof. Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorJishan Wu Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorMartin Baumgarten Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorMichael G. Debije Dr.
IRI, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands
Search for more papers by this authorJohn M. Warman Prof. Dr.
IRI, Delft University of Technology, Mekelweg 15, 2629 JB Delft, The Netherlands
Search for more papers by this authorKlaus Müllen Prof. Dr.
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, 55128 Mainz, Germany, Fax: (+49) 6131-379-350
Search for more papers by this authorThis work was financially supported by the Zentrum für Multifunktionelle Werkstoffe und Miniaturisierte Funktionseinheiten (BMBF 03N 6500), the Deutsche Forschungsgemeinschaft (Schwerpunkt Organische Feldeffekttransistoren, as well as the EU project DISCELs (G5RD-CT-2000-00321) and MAC-MES (Grd2-2000-30242).
Graphical Abstract
The hole story: using a new synthetic concept the title hexa-peri-hexabenzocoronenes (HBCs) were synthesized with high atom economy. The coaxial arrangement of the HBCs and arylamines allowed a “double-cable” hole transport (see picture), that is, transport through the central core (white) and the outer shell (green).
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Citing Literature
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