Angewandte Chemie International Edition in English

Volume 24, Issue 10 pp. 869-870

Communication

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Cl₂CClCl^⊙⊕, Cl₂CClBr^⊙⊕, and Br₂CBrCl^⊙⊕ by Gas-Phase Decarbonylation of CX₃COY^⊙⊕^†^‡

Thomas Drewello,

Thomas Drewello

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

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Dr. Thomas Weiske,

Dr. Thomas Weiske

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

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Prof. Dr. Helmut Schwarz,

Corresponding Author

Prof. Dr. Helmut Schwarz

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12Search for more papers by this author

Thomas Drewello,

Thomas Drewello

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

Search for more papers by this author

Dr. Thomas Weiske,

Dr. Thomas Weiske

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

Search for more papers by this author

Prof. Dr. Helmut Schwarz,

Corresponding Author

Prof. Dr. Helmut Schwarz

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12

Institut für Organische Chemie der Technischen Universität, Strasse des 17. Juni 135, D-1000 Berlin 12Search for more papers by this author

First published: October 1985

https://doi.org/10.1002/anie.198508691

Citations: 21

^†

This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.

^‡

Dedicated to Professor Rolf Huisgen on the occasion of his 65th birthday

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Abstract

The long-sought radical cation of carbon tetrachloride has been generated by decarbonylation of Cl₃CCOCl^⊙⊕ in the gas phase and characterized as the stable isomer Cl₂CClCl^⊙⊕. The theoretically predicted properties were experimentally confirmed. The dication CCl urn:x-wiley:05700833:media:ANIE198508691:tex2gif-stack-1 is known.

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Volume24, Issue10

October 1985

Pages 869-870

Cl₂CClCl^⊙⊕, Cl₂CClBr^⊙⊕, and Br₂CBrCl^⊙⊕ by Gas-Phase Decarbonylation of CX₃COY^⊙⊕^†^‡

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Cl2CClCl⊙⊕, Cl2CClBr⊙⊕, and Br2CBrCl⊙⊕ by Gas-Phase Decarbonylation of CX3COY⊙⊕†‡

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Cl₂CClCl^⊙⊕, Cl₂CClBr^⊙⊕, and Br₂CBrCl^⊙⊕ by Gas-Phase Decarbonylation of CX₃COY^⊙⊕^†^‡