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Bond Switch with Participation of π-Bonded S^IV in Thiathiophthene-Analogous Systems^†

Corresponding Author

Prof. Dr. Kin-ya Akiba

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)Search for more papers by this author

Dipl. Chem. Shin-ichi Arai,

Dipl. Chem. Shin-ichi Arai

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Dr. Tohru Tsuchiya,

Dr. Tohru Tsuchiya

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Yohsuke Yamamoto,

Yohsuke Yamamoto

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Prof. Dr. Fujiko Iwasaki,

Prof. Dr. Fujiko Iwasaki

Department of Materials Science, The University of Electro-Communications Chofu-shi, Tokyo 182 (Japan)

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Prof. Dr. Kin-ya Akiba,

Corresponding Author

Prof. Dr. Kin-ya Akiba

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)Search for more papers by this author

Dipl. Chem. Shin-ichi Arai,

Dipl. Chem. Shin-ichi Arai

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Dr. Tohru Tsuchiya,

Dr. Tohru Tsuchiya

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Yohsuke Yamamoto,

Yohsuke Yamamoto

Department of Chemistry, Faculty of Science. The University of Tokyo, Hongo, Tokyo 113 (Japan)

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Prof. Dr. Fujiko Iwasaki,

Prof. Dr. Fujiko Iwasaki

Department of Materials Science, The University of Electro-Communications Chofu-shi, Tokyo 182 (Japan)

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First published: February 1979

https://doi.org/10.1002/anie.197901661

Citations: 25

^†

This work was supported in part by the Itoh Science Foundation.

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Dynamic bond switching at π-hypervalent sulfur has now been demonstrated. (1) and (2) rapidly equilibrate; this reaction involves the thiathiophtheneanalogous system (3).

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