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Stepwise Addition of a Lewis Acid and a Lewis Base to a Metal-Metal Bond^†

Corresponding Author

Prof. Dr. Helmut Werner

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)Search for more papers by this author

Dipl.-Chem. Werner Hofmann,

Dipl.-Chem. Werner Hofmann

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)

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Prof. Dr. Helmut Werner,

Corresponding Author

Prof. Dr. Helmut Werner

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)Search for more papers by this author

Dipl.-Chem. Werner Hofmann,

Dipl.-Chem. Werner Hofmann

Institut für Anorganische Chemie der Universität, Am Hubland, D-8700 Würzburg (Germany)

Search for more papers by this author

First published: February 1979

https://doi.org/10.1002/anie.197901581

Citations: 23

^†

Basic Metals, Part 17, This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and by donations of chemicals from BASF, Ludwigshafen, and Bayer AG, Leverkusen. We wish to thank J. Wolf for experimental assistance.—part 16: A. Spencer, H. Werner, J. Organomet. Chem., in press.

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Graphical Abstract

Cleavage of the CoCo bond in the complex is feasible without disrupting the binuclear structure. Thus a Lewis acid, e.g. CF₃COOH, and a Lewis base. e.g. PMe₃, can be added successively to (1).

References

1 Basic Metals, Part 17, This work was supported by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie and by donations of chemicals from BASF, Ludwigshafen, and Bayer AG, Leverkusen. We wish to thank J. Wolf for experimental assistance.—part 16: A. Spencer, H. Werner, J. Organomet. Chem., in press.
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Volume18, Issue2

February 1979

Pages 158-159

Stepwise Addition of a Lewis Acid and a Lewis Base to a Metal-Metal Bond^†

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Stepwise Addition of a Lewis Acid and a Lewis Base to a Metal-Metal Bond†

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Stepwise Addition of a Lewis Acid and a Lewis Base to a Metal-Metal Bond^†