Anion-π Interactions on Functionalized Porous Aromatic Cages for Gold Recovery from Complex Aqueous with High Capacity
Dr. Jianzhu Jiang
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Junning Kou
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Qi Wu
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorDr. Li Chen
Department of Chemistry, Faculty of Science, Yanbian University Yanji, Jilin, 133002 China
Search for more papers by this authorProf. Dr. Yun Geng
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorProf. Dr. Guogang Shan
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Chunyi Sun
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorProf. Dr. Zhongmin Su
State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, 130024 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xinlong Wang
State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, 130024 China
Search for more papers by this authorDr. Jianzhu Jiang
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Junning Kou
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
These authors contributed equally to this work.
Search for more papers by this authorDr. Qi Wu
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorDr. Li Chen
Department of Chemistry, Faculty of Science, Yanbian University Yanji, Jilin, 133002 China
Search for more papers by this authorProf. Dr. Yun Geng
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorProf. Dr. Guogang Shan
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Chunyi Sun
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, National & Local United Engineering Laboratory for Power Battery Institution, Northeast Normal University, Changchun, Jilin, 130024 China
Search for more papers by this authorProf. Dr. Zhongmin Su
State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, 130024 China
Search for more papers by this authorCorresponding Author
Prof. Dr. Xinlong Wang
State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, 130024 China
Search for more papers by this authorAbstract
High capacity, selective recovery and separation of precious metals from complex aqueous solutions is essential but remains a challenge in practical applications. Here, we prepared a thiophene-modified aromatic porous organic cage (T-PAC) with high stability for precise recognition and recovery of gold. T-PAC exhibits an outstanding gold uptake capacity of up to 2260 mg/g with fast adsorption kinetics and high adsorption selectivity. It's also used to selectively recover gold from a variety of complex aqueous solutions in a stable and efficient manner. The theoretical calculations and dedicated experiments suggest that anion-π interactions between the [AuCl4]− and TFP fractions on T-PAC cooperated with S/N boning and redox effects play the decisive role in the highly efficient gold recovery performance.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the Supporting Information of this article.
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