Volume 136, Issue 48 e202410342

Forschungsartikel

A High Capacity p-Type Organic Cathode Material for Aqueous Zinc Batteries

Yan Zhang

Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, College of Environmental and Chemical Engineering, Shanghai University of Electric Power, 200090 Shanghai, China

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Min Li,

Min Li

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Zongyang Li,

Zongyang Li

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Yongyi Lu,

Yongyi Lu

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Houmou Li,

Houmou Li

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Jiaxin Liang,

Jiaxin Liang

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Xinyu Hu,

Xinyu Hu

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Libin Zhang,

Libin Zhang

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Dr. Kun Ding,

Corresponding Author

Dr. Kun Ding

[email protected]

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Prof. Qunjie Xu,

Prof. Qunjie Xu

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Prof. Dr. Haimei Liu,

Corresponding Author

Prof. Dr. Haimei Liu

[email protected]

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Prof. Yonggang Wang,

Corresponding Author

Prof. Yonggang Wang

[email protected]

orcid.org/0000-0002-2447-4679

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, 200433 Shanghai, China

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Yan Zhang,

Yan Zhang

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Min Li,

Min Li

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Zongyang Li,

Zongyang Li

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Yongyi Lu,

Yongyi Lu

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Houmou Li,

Houmou Li

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Jiaxin Liang,

Jiaxin Liang

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Xinyu Hu,

Xinyu Hu

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Libin Zhang,

Libin Zhang

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Dr. Kun Ding,

Corresponding Author

Dr. Kun Ding

[email protected]

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Prof. Qunjie Xu,

Prof. Qunjie Xu

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Prof. Dr. Haimei Liu,

Corresponding Author

Prof. Dr. Haimei Liu

[email protected]

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Prof. Yonggang Wang,

Corresponding Author

Prof. Yonggang Wang

[email protected]

orcid.org/0000-0002-2447-4679

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, 200433 Shanghai, China

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First published: 02 September 2024

https://doi.org/10.1002/ange.202410342

Citations: 3

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Abstract

P-type organic cathode materials typically exhibit high redox potentials and fast redox kinetics, presenting broad application prospects in aqueous zinc batteries (AZBs). However, most of the reported p-type organic cathode materials exhibit limited capacity (<100 mAh g⁻¹), which is attributable to the low mass content ratio of oxidation-reduction active functional groups in these materials. Herein, we report a high-capacity p-type organic material, 5,12-dihydro-5,6,11,12-tetraazatetracene (DHTAT), for aqueous zinc batteries. Both experiments and calculation indicate the charge storage of DHTAT mainly involves the adsorption/desorption of ClO₄⁻ on the −NH− group. Benefitting from the high mass content ratio of the −NH− group in DHATA molecule, the DHATA electrode demonstrates a remarkable capacity of 224 mAh g⁻¹ at a current density of 50 mA g⁻¹ with a stable voltage of 1.12 V. Notably, after 5000 cycles at a high current density of 5 A g⁻¹, DHTAT retains 73 % of its initial capacity, showing a promising cycling stability. In addition, DHTAT also has good low-temperature performance and can stably cycle at −40 °C for 4000 cycles at 1 A g⁻¹, making it a competitive candidates cathode material for low-temperature batteries.

Conflict of Interests

The authors declare no conflict of interest.

Open Research

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Supporting Information

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November 25, 2024

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A High Capacity p-Type Organic Cathode Material for Aqueous Zinc Batteries

Abstract

Conflict of Interests

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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A High Capacity p-Type Organic Cathode Material for Aqueous Zinc Batteries

Abstract

Conflict of Interests

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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