Switchable and Highly Robust Ultralong Room-Temperature Phosphorescence from Polymer-Based Transparent Films with Three-Dimensional Covalent Networks for Erasable Light Printing
Jian-An Li
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorLetian Zhang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorDr. Chunlei Wu
Guangzhou Huifu Research Institute Co., Ltd., Guangzhou, 510663 China
Search for more papers by this authorZihao Huang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorShufeng Li
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorHuaqing Zhang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorQingchen Yang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Dr. Zhu Mao
Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Search for more papers by this authorProf. Suilian Luo
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorProf. Cong Liu
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Prof. Guang Shi
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Prof. Bingjia Xu
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorJian-An Li
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorLetian Zhang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorDr. Chunlei Wu
Guangzhou Huifu Research Institute Co., Ltd., Guangzhou, 510663 China
Search for more papers by this authorZihao Huang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorShufeng Li
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorHuaqing Zhang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorQingchen Yang
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Dr. Zhu Mao
Shenzhen Institute of Advanced Electronic Materials, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China
Search for more papers by this authorProf. Suilian Luo
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorProf. Cong Liu
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Prof. Guang Shi
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorCorresponding Author
Prof. Bingjia Xu
School of Chemistry, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, South China Normal University, Guangzhou, 510006 China
Search for more papers by this authorAbstract
In this work, an efficient polymer-based organic afterglow system, which shows reversible photochromism, switchable ultralong organic phosphorescence (UOP), and prominent water and chemical resistance simultaneously, has been developed for the first time. By doping phenoxazine (PXZ) and 10-ethyl-10H-phenoxazine (PXZEt) into epoxy polymers, the resulting [email protected] % and [email protected] % films show unique photoactivated UOP properties, with phosphorescence quantum yields and lifetimes up to 10.8 % and 845 ms, respectively. It is found that the steady-state luminescence and UOP of [email protected] % are switchable by light irradiation and thermal annealing. Moreover, the doped films can still produce conspicuous UOP after soaking in water, strong acid and base, and organic solvents for more than two weeks, exhibiting outstanding water and chemical resistance. Inspired by these exciting results, the [email protected] % has been successfully exploited as an erasable transparent film for light printing.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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| ange202217284-sup-0001-SI_supporting_information-Video_S2-PXZ@EP-After_Photoactivation.mp41 MB | Supporting Information |
| ange202217284-sup-0001-SI_supporting_information-Video_S3-PXZEt@EP-After_Activation.mp4476.5 KB | Supporting Information |
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