ZnF2-Riched Inorganic/Organic Hybrid SEI: in situ-Chemical Construction and Performance-Improving Mechanism for Aqueous Zinc-ion Batteries
Dan Xie
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorYuan Sang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDan-Hong Wang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorWan-Yue Diao
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorFang-Yu Tao
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorChang Liu
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jia-Wei Wang
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, 130012 P. R. China
Search for more papers by this authorProf. Hai-Zhu Sun
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jing-Ping Zhang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xing-Long Wu
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorDan Xie
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorYuan Sang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
These authors contributed equally to this work.
Search for more papers by this authorDan-Hong Wang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorWan-Yue Diao
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorFang-Yu Tao
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorChang Liu
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jia-Wei Wang
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, 130012 P. R. China
Search for more papers by this authorProf. Hai-Zhu Sun
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Jing-Ping Zhang
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Xing-Long Wu
Faculty of Chemistry, Northeast Normal University, Changchun, 130024 P. R. China
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun, 130024 P. R. China
Search for more papers by this authorAbstract
Uncontrolled dendrites growth and serious parasitic reactions in aqueous electrolytes, greatly hinder the practical application of aqueous zinc-ion battery. On the basis of in situ-chemical construction and performance-improving mechanism, multifunctional fluoroethylene carbonate (FEC) is introduced into aqueous electrolyte to construct a high-quality and ZnF2-riched inorganic/organic hybrid SEI (ZHS) layer on Zn metal anode (ZMA) surface. Notably, FEC additive can regulate the solvated structure of Zn2+ to reduce H2O molecules reactivity. Additionally, the ZHS layer with strong Zn2+ affinity can avoid dendrites formation and hinder the direct contact between the electrolyte and anode. Therefore, the dendrites growth, Zn corrosion, and H2 evolution reaction on ZMA in FEC-included ZnSO4 electrolyte are highly suppressed. Thus, ZMA in such electrolyte realize a long cycle life over 1000 h and deliver a stable coulombic efficiency of 99.1 % after 500 cycles.
Conflict of interest
There are no conflicts to declare.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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