Facet-Dependent Oxidative Strong Metal-Support Interactions of Palladium–TiO2 Determined by In Situ Transmission Electron Microscopy
Dr. Min Tang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Materials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, 3584 CG Utrecht, The Netherlands
Search for more papers by this authorSongda Li
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorShiyuan Chen
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorYang Ou
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorMatsumoto Hiroaki
Hitachi High-Tech (Shanghai) Co., Ltd., Shanghai, 201203 China
Search for more papers by this authorDr. Wentao Yuan
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorDr. Beien Zhu
Interdisciplinary Research Center, Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese, Academy of Sciences, Shanghai, 201210 China
Search for more papers by this authorProf. Hangsheng Yang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorProf. Yi Gao
Interdisciplinary Research Center, Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese, Academy of Sciences, Shanghai, 201210 China
Search for more papers by this authorProf. Ze Zhang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Yong Wang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorDr. Min Tang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Materials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, 3584 CG Utrecht, The Netherlands
Search for more papers by this authorSongda Li
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorShiyuan Chen
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorYang Ou
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorMatsumoto Hiroaki
Hitachi High-Tech (Shanghai) Co., Ltd., Shanghai, 201203 China
Search for more papers by this authorDr. Wentao Yuan
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorDr. Beien Zhu
Interdisciplinary Research Center, Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese, Academy of Sciences, Shanghai, 201210 China
Search for more papers by this authorProf. Hangsheng Yang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorProf. Yi Gao
Interdisciplinary Research Center, Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese, Academy of Sciences, Shanghai, 201210 China
Search for more papers by this authorProf. Ze Zhang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorCorresponding Author
Prof. Yong Wang
Center of Electron Microscopy and State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027 China
Search for more papers by this authorAbstract
The strong metal-support interaction (SMSI) is widely used in supported metal catalysts and extensive studies have been performed to understand it. Although considerable progress has been achieved, the surface structure of the support, as an important influencing factor, is usually ignored. We report a facet-dependent SMSI of Pd-TiO2 in oxygen by using in situ atmospheric pressure TEM. Pd NPs supported on TiO2 (101) and (100) surfaces showed encapsulation. In contrast, no such cover layer was observed in Pd-TiO2 (001) catalyst under the same conditions. This facet-dependent SMSI, which originates from the variable surface structure of the support, was demonstrated in a probe reaction of methane combustion catalyzed by Pd-TiO2. Our discovery of the oxidative facet-dependent SMSI gives direct evidence of the important role of the support surface structure in SMSI and provides a new way to tune the interaction between metal NPs and the support as well as catalytic activity.
Conflict of interest
The authors declare no conflict of interest.
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