Topological-Distortion-Driven Amorphous Spherical Metal-Organic Frameworks for High-Quality Single-Mode Microlasers
Corresponding Author
Dr. Zhenhua Gao
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorBaoyuan Xu
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorYuqing Fan
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorTongjin Zhang
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorDr. Shunwei Chen
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorShuo Yang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorWeiguang Zhang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorXun Sun
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorProf. Yanhui Wei
College of Chemistry and Material Science, Shandong Agricultural University, Taian, 271018 Shandong, China
Search for more papers by this authorDr. Zifei Wang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorDr. Xue Wang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorCorresponding Author
Prof. Xiangeng Meng
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorCorresponding Author
Prof. Yong Sheng Zhao
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorCorresponding Author
Dr. Zhenhua Gao
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorBaoyuan Xu
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorYuqing Fan
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorTongjin Zhang
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorDr. Shunwei Chen
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorShuo Yang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorWeiguang Zhang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorXun Sun
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorProf. Yanhui Wei
College of Chemistry and Material Science, Shandong Agricultural University, Taian, 271018 Shandong, China
Search for more papers by this authorDr. Zifei Wang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorDr. Xue Wang
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorCorresponding Author
Prof. Xiangeng Meng
School of Materials Science & Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353 Shandong Province, China
Search for more papers by this authorCorresponding Author
Prof. Yong Sheng Zhao
Key Laboratory of photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 China
Search for more papers by this authorAbstract
Metal-organic frameworks (MOFs) have recently emerged as appealing platforms to construct microlasers owing to their compelling characters combining the excellent stability of inorganic materials and processable characters of organic materials. However, MOF microstructures developed thus far are generally composed of multiple edge boundaries due to their crystalline nature, which consequently raises significant scattering losses that are detrimental to lasing performance. In this work, we propose a strategy to overcome the above drawback by designing spherically shaped MOFs microcavities. Such spherical MOF microstructures are constructed by amorphizing MOFs with a topological distortion network through introducing flexible building blocks into the growth environment. With an ultra-smooth surface and excellent circular boundaries, the acquired spherical microcavities possess a Q factor as high as ≈104 and can provide sufficient feedback for high-quality single-mode lasing oscillations. We hope that these results will pave an avenue for the construction of new types of flexible MOF-based photonic components.
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